2009
DOI: 10.1016/j.apsusc.2008.11.070
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Direct writing of carbon nanotube patterns by laser-induced chemical vapor deposition on a transparent substrate

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Cited by 14 publications
(15 citation statements)
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“…This is a result of the change in surface energy and wetting properties of the catalyst 75 as well as the different heat distribution through the subcatalyst layer and substrate. 76,77 On top of that, transparency of the substrate for certain wavelengths is another property that significantly influences the growth method that can be used. The most commonly used substrate is silicon, although fused silica, [76][77][78] graphite and grafoil, 79 and porous Al 2 O 3 membranes 80,81 were also used in combination with laser-assisted growth.…”
Section: A Catalyst and Substratementioning
confidence: 99%
See 1 more Smart Citation
“…This is a result of the change in surface energy and wetting properties of the catalyst 75 as well as the different heat distribution through the subcatalyst layer and substrate. 76,77 On top of that, transparency of the substrate for certain wavelengths is another property that significantly influences the growth method that can be used. The most commonly used substrate is silicon, although fused silica, [76][77][78] graphite and grafoil, 79 and porous Al 2 O 3 membranes 80,81 were also used in combination with laser-assisted growth.…”
Section: A Catalyst and Substratementioning
confidence: 99%
“…76,77 On top of that, transparency of the substrate for certain wavelengths is another property that significantly influences the growth method that can be used. The most commonly used substrate is silicon, although fused silica, [76][77][78] graphite and grafoil, 79 and porous Al 2 O 3 membranes 80,81 were also used in combination with laser-assisted growth. Shi et al 82 synthesized suspended multiwall (650 C) as well as single-wall (770 C) nanotubes on inverse opal templates of silicon covered with a NiFe catalyst.…”
Section: A Catalyst and Substratementioning
confidence: 99%
“…This can lead to detrimental positive optical feedback, whereby the sample quickly overheats at the center of the laser spot, leading to uncontrolled inhomogeneous growth. 14,16 Here, we introduce the concept of a co-catalytic absorption layer structure for controlled LiCVD, in which a thin CNT catalyst support layer chemically aids the initial catalyst reduction and hence enables a significant reduction of the applied laser power, preventing detrimental positive optical feedback and allowing improved growth control. We focus on Ta mediated solid-state reduction of Fe catalysts 27 and systematically investigate the interplay of light absorption and heat conduction for varying Ta support layer thickness to establish general guidelines for the effective design of catalyst/ absorption layer combinations in LiCVD.…”
Section: ■ Introductionmentioning
confidence: 99%
“…2(d). With higher temperature, burn-out phenomenon [7] could occur for the as-grown CNTs. For further higher temperature, even SMS can be permanently destroyed due to overheating, as shown in Fig.…”
Section: Resultsmentioning
confidence: 98%