2015
DOI: 10.1016/j.apsusc.2015.09.200
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Direct surface PEGylation of nanodiamond via RAFT polymerization

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Cited by 39 publications
(20 citation statements)
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“…Surface-initiated living radical polymerization reactions provide a good alternative for the biomedical materials surface modification, as obtaining the well-defined polymer brushes. Reversible addition-fragmentation chain transfer (RAFT) polymerization is one of the living radical polymerization techniques and it has enjoyed widespread acceptance as a modification technique due to its capability to control polymerization of diverse monomers under mild reaction conditions without the requirement of metal catalysts [12][13][14]. Antifouling surface can be obtained via surfaceinitiated RAFT polymerization of antifouling molecules on the material surface [15][16][17].…”
Section: Introductionmentioning
confidence: 99%
“…Surface-initiated living radical polymerization reactions provide a good alternative for the biomedical materials surface modification, as obtaining the well-defined polymer brushes. Reversible addition-fragmentation chain transfer (RAFT) polymerization is one of the living radical polymerization techniques and it has enjoyed widespread acceptance as a modification technique due to its capability to control polymerization of diverse monomers under mild reaction conditions without the requirement of metal catalysts [12][13][14]. Antifouling surface can be obtained via surfaceinitiated RAFT polymerization of antifouling molecules on the material surface [15][16][17].…”
Section: Introductionmentioning
confidence: 99%
“…Polyethylene glycol (PEG) along with its methacrylate derivatives and hyperbranched polyglycerol (PG) are typical examples of polymers investigated to form hydrophilic shells on the surface of DNDs which have been successfully used to increase their stability in aqueous solution [26, 27]. …”
Section: Synthesis and Functionalization Of Ndsmentioning
confidence: 99%
“…Apart from carbodiimide chemistry, which has been applied for covalent conjugation with PLL, PEG, fructose polymers, and others, three different types of surface‐initiated polymerization methods have been established for surface modification of NDs and FNDs: (a) atom transfer radical polymerization, (b) reversible addition‐fragmentation chain transfer polymerization, and (c) ring‐opening polymerization . Specifically, Komatsu and coworkers developed a method of grafting hyperbranched polyglycerol (PG) on the ND surface via ring‐opening reactions of glycidol .…”
Section: Biohybrid Fndsmentioning
confidence: 99%