“…It exhibits an indirect band gap of ∼1.4 eV in the bulk form and transforms to a direct-band-gap semiconductor (band gap: ∼2.1 eV) in its monolayer limit. , As a result, the effective barrier height in graphene–WS 2 –graphene (GWG) heterostructures is suitable for effective carrier tunneling, and the change in the Fermi level of graphene is comparable to the barrier height, leading to high-performance GWG tunneling transistors with an ON/OFF ratio much higher than FETTs based on graphene–hBN–graphene or graphene–MoTe 2 –graphene heterostructures . A few studies have reported the tunneling devices based on GWG heterostructures, demonstrating high ON/OFF ratio, light emission, and negative differential resistance. ,,, However, a systematic exploration of the electronic properties of GWG tunneling transistors, including the band alignment, the bias-controlled barrier shape, height, and the transition from direct tunneling to Fowler–Nordheim tunneling, is still lacking.…”