Digital simulation of chronoamperometry at a disk electrode under a flat polymer film containing an enzyme

Thermolysin entrapped in a gold nanoparticles/polymer composite for direct and sensitive conductometric biosensing of ochratoxin A in olive oil

“…The observed cooperativity phenomenon could be explained by OTA transfer constraint from macroenvironment to the electrode microenvironment coupled to TLN-catalyzed hydrolysis. It is likely that a more complex model including not only Michaelis-Menten but also diffusion terms should be used to fit data in this case [72].…”