“…(2) also predicts that the measured capacitance should be decreased with the increasing frequency and it reaches to a constant value at the higher frequency [19][20][21]. This behavior can be attributed to the effect of charge redistribution by carrier hopping on defects [22,23]. At the lower frequencies, the charge on the defects can be rapidly redistributed, so that the defects closer to the positive side of the applied field become negatively charged, while the defects closer to the negative side of the applied field become positively charged.…”
“…(2) also predicts that the measured capacitance should be decreased with the increasing frequency and it reaches to a constant value at the higher frequency [19][20][21]. This behavior can be attributed to the effect of charge redistribution by carrier hopping on defects [22,23]. At the lower frequencies, the charge on the defects can be rapidly redistributed, so that the defects closer to the positive side of the applied field become negatively charged, while the defects closer to the negative side of the applied field become positively charged.…”
“…1. This behavior can be attributed to the effect of charge redistribution by carrier hopping on defects [33][34][35]. At the lower frequency, the charge on the defects can be rapidly redistributed, so that defects closer to the positive side of the applied field become negatively charged, while defects closer to the negative side of the applied field become positively charged.…”
“…According to Eq. (4), the increase of capacitance C with temperature may be due to decrease of the sample resistance R with temperature [32]. This behavior can be attributed to the eect of charge redistribution by mean carrier hopping on defects [3335].…”
Section: Temperature and Frequency Dependences Of The Measured Capacimentioning
X-ray diraction pattern of 4-aminoantipyrine was studied and it is a single phase with a polycrystalline structure. 4-aminoantipyrine has hexagonal structure with space group P 6/mcc. The electrical properties of 4-aminoantipyrine were studied in the temperature range (303373 K) below the melting point of the studied compound and in the frequency range (100 Hz100 kHz). The obtained results of dc conductivity showed a positive temperature coecient at the lower temperatures and a negative temperature coecient at the higher temperatures. The ac conductivity obeys the power law. Ac conductivity can be reasonably interpreted in terms of overlapping-large polaron tunneling model and the correlated barrier hopping model. 4-aminoantipyrine is a good candidate for electronic device due to its electrical conductivity and capacitance.
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