0.35Pb(Ni 1/3 Nb 2/3 )O 3 -0.65Pb(Zr 0.41 Ti 0.59 )O 3 (PNN-PZT) ceramics doped with 0.5PbO-0.5B 2 O 3 glass have been synthesized by the conventional solid-state sintering technique. The effects of 0.5PbO-0.5B 2 O 3 glass on the sintering temperature and piezoelectric properties of PNN-PZT ceramics were studied. The results indicated that the sintering temperature of PNN-PZT was significantly reduced due to the incorporation of 0.5PbO-0.5B 2 O 3 glass dopant. When the content of 0.5PbO-0.5B 2 O 3 glass was 0.5 wt.%, the sintering temperature of PNN-PZT was observed to reduce from above 1200°C to 920°C while the samples maintained high density (7.91 g/cm 3 ), excellent piezoelectric constant (d 33 = 479 pC/N), large electromechanical coupling coefficient (K p = 0.55), and relatively low electromechanical quality factor (Q m = 79). Moreover, large dielectric constant (e 33 T /e 0 = 2904) and low dielectric loss (tan d = 0.0166) were obtained in this work.