Die Zersetzung des Kohlenoxychlorides in der Wärme. II

Stock, Alfred; Wustrow, Werner; Lux, Hermann; Ramser, Hans

doi:10.1002/zaac.19311950116

Cited by 9 publications

(4 citation statements)

References 8 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The constant volume small bomb results of Stock (21) are naturally not of the same degree of accuracy as these based on the dynamic method. Stock could only produce a few hundredths of a cubic centimeter of phosgene in a bomb.…”

Section: Methodsmentioning

confidence: 92%

“…Stock has already shown that concentrated potassium hydroxide solution can effectively dissolve phosgene and carbon dioxide without hydrolyzing carbon tetrachloride appreciably, nor dissolving it. The reverse reaction of the one just discussed, or the formation of phosgene from carbon dioxide and carbon tetrachloride, was next taken up, to attempt to reach the equilibrium experimentally from that side, and to improve on the few and rather unreproducible data of Stock (21).…”

Section: The Direct Chlorination Of Carbonmentioning

confidence: 99%

See 1 more Smart Citation

A Study of Several Reactions of Carbon Tetrachloride Synthesis.

Fine¹,

Bonilla²

1933

J. Phys. Chem.

View full text Add to dashboard Cite

Section: Methodsmentioning

confidence: 92%

Section: The Direct Chlorination Of Carbonmentioning

confidence: 99%

A Study of Several Reactions of Carbon Tetrachloride Synthesis.

Fine¹,

Bonilla²

1933

J. Phys. Chem.

View full text Add to dashboard Cite

“…These conditions are met by the decomposition of phosgene into carbon tetrachloride and carbori dioxide: 2 c:oc12 ; ! cc14 c coz (2) …”

Section: Preparation Of Carbonmentioning

confidence: 99%

“…Ketenes were first investigated by Sfaudinger, who synthetized diphenylketene and dimethylketene [ 1,2]. The parent compound of this class of substances, ketene [3], was prepared a few years later and became an im- [I] H. Stuudinger, Ber.…”

Section: Introductionmentioning

confidence: 99%

An Acylal of Dimethylketene

Bestian¹,

Günther²

1963

Angew. Chem. Int. Ed. Engl.

View full text Add to dashboard Cite

Further preparative and kinetic studies are necessary before it can be decided whether N-halogen compounds (R-NHX) react via nitrenes or by a nucleophilic substitution mechanism. The same is true for the conversion with ferrous oxalate at about 300 "C of 0-nitrobiphenyl [72] or o-nitrobiphenylamine [73] into carbazole (58) and 9,lO-dihydrophenazine (59), respectively, and for the transformation of 2-(o-nitrophenyl)pyridine into ammonium nitreniate (60). The latter is also formed on thermal decomposition but not on exposure to ultraviolet radiation of 2-(o-azidophenyl)pyridine [74].

show abstract

Verfahren zur Herstellung von Tetrachlorkohlenstoff aus Phosgen

et al. 1963

View full text Add to dashboard Cite

nicht mehr restlos in Benzol, was durch Bildung hoherer Polymere [(PO)z(PPh),], (n > 2) zu erklaren ist. Das 1R-Spektrum von P404(PPh)6 stimmt niit dem von P4(PPh)6 uberein, mit dem Unterschied, daR zusatzlich eine P-0-Bande bei 8 p beobachtet wird. SchluDFaRt man die in den Abschnitten I bis V beschriebenen Ergebnisse zusammen, so kann man feststellen, daR der Phosphor gleich seinen beiden Nachbarn im Periodensystem, dern Silicium und Schwefel, hohergliedrige Ketten-und Ring-Molekule zu bilden verrnag. Die weitere Forschung auf diesem Gebiete verspricht daher eine reiche Ernte und wird sicherlich nicht nur zur SchlieRung systematischer Lucken, sondern auch zur Erweiterung unserer Vorstellungen vom Bindungs-und Reaktionsverhalten des Phosphors beitragen. lnsbesondere laBt sich aus den bisherigen Untersuchungen uber organosubstituierte Polyphosphane PnR, + die Hoffnung ableiten, daB a u k r dem bis heute allein bekannten Grundkorper P2H4 auch hohere geradkettige Polyphosphane PnHn + ?, wie P3H5 und P4H6, bei tieferer Temperatur isolierbar sein werden. Vielversprechende Hinweise hierfur finden sich bereits in der Literatur [27].

show abstract

Die Zersetzung des Kohlenoxychlorides in der Wärme. II

Cited by 9 publications

References 8 publications

A Study of Several Reactions of Carbon Tetrachloride Synthesis.

A Study of Several Reactions of Carbon Tetrachloride Synthesis.

An Acylal of Dimethylketene

Verfahren zur Herstellung von Tetrachlorkohlenstoff aus Phosgen

Contact Info

Product

Resources

About