A reversed magnetic shear high plasma performance H-mode discharge with internal transport barrier (ITB) has been realized and modeled on experimental advanced superconducting tokamak (EAST) in deuterium (D) plasmas with an ITER-like tungsten (W) upper divertor. In this shot (#71326), the dimensionless parameter G (
H
89
β
N
/
q
95
2
) can reach to 0.25 (H
89 ⩽ 2, β
N ⩽ 2, q
95 ∼ 4, I
p ⩽ 450 kA, B
T ⩽ 1.6 T). The ITB has been observed in the channels of particle (electron density n
e), electron and ion temperature (T
e and T
i) and toroidal rotation velocity (V
t). However, in the formation process of V
t and n
e ITBs, the heavy impurities accumulate in the core plasmas, which may be one of the most important reasons for the limitation of the improvement of plasma performance. A time slice (t = 4.65 s) of the high plasma performance phase with n
e, T
i and V
t ITBs has been analyzed. It is found that the position of minimum safety factor (q
min) is at about normalized radius ρ = 0.4 where may be the location of ion ITB foot, during equilibrium reconstruction from EFIT using external magnetic and internal polarimeter-INTferometer (POINT) measurement constraints. Based on this equilibrium, the source is self-consistently calculated by ONETWO and NUBEAM. Then the n
e, T
e, T
i and V
t have been modeled predictively and simultaneously by TGYRO utilizing the reconstructed equilibrium, the self-consistent source and the experimental radiated power for the first time in EAST. This modeling well reproduces the experimental n
e and T
i profiles in the reversed magnetic shear plasmas. In addition, it is shown that reversed magnetic shear rather than shear of radial electric field (E
r) mainly produced by V
t plays a key role to the formation of n
e and T
i ITBs. The reasons for central accumulation of W impurity are also clarified by computing both neoclassical and turbulent transport components of W. It turns out that the neoclassical transport dominates over turbulent transport for W and neoclassical pinch of W causes its central accumulation.