“…Peak 15 gave a pseudo molecular ion, [M-H]ˉ, at m/z 582, which yielded ions at m/z 462, 436, 342, 299, 316, 145, and 119. This fragmentation pattern was fully matched by the previously identified N1,N5,N10-tri-p-(E,E,E)-coumaroyl spermidine [28][29][30][31]. Peak 16 at t R 37.12 min was confirmed as apigenin (m/z 269, 149, 117 and commercial apigenin standard).…”