Determination of Bisphenol A in Plastic Bottled Drinking Water by High Performance Liquid Chromatography with Solid-membrane Extraction Based on Electrospun Nylon 6 Nanofibrous Membrane

Development and validation of a nylon6 nanofibers mat-based SPE coupled with HPLC method for the determination of docetaxel in rabbit plasma and its application to the relative bioavailability study

“…The experiment results showed that the enrichment efficiencies of target analytes changed with pH were not obvious in the range of 4.0-9.0. While the pH was 3.0, recovery obviously decreased, for nylon6 may become protonated at pH ≤ 3 owing to -NH-group, and the structure and appearance of the fibers would be destroyed [33]. The recovery was also low when the pH was 10.0.…”

Simultaneous determination of five phthalate esters and bisphenol A in milk by packed‐nanofiber solid‐phase extraction coupled with gas chromatography and mass spectrometry

“…Xu et al. have successfully used nylon 6 nanofibers mats as adsorption material packed in a disk for the determination of PAEs in edible oil, water, and milk , however, the microcolumn packing system proved to be superior to the disk format consistently by Possi‐Pezzali et al. because of higher recoveries, and the difference in the number of theoretical plates that is probably owing to the different geometries of the devices.…”

“…Compared with the conventional SPE technique, the nanometer material exhibits extraordinary properties such as small fiber diameter, large surface area, and high porosity as well as easy surface modification, which not only decrease amounts of sorbent but also reduce the volume of sample and organic solvents [14]. Xu et al have successfully used nylon 6 nanofibers mats as adsorption material packed in a disk for the determination of PAEs in edible oil, water, and milk [14][15][16][17], however, the microcolumn packing system proved to be superior to the disk format consistently by Possi-Pezzali et al [18] because of higher recoveries, and the difference in the number of theoretical plates that is probably owing to the different geometries of the devices. In our previous work, the polystyrene (PS) nanofiber was used to enrich PAEs in urinary samples [19], although the satisfied recoveries and LOD were obtained, the selectivity and anti-interference need to be further improved.…”

Nylon 6 electrospun nanofibers mat as effective sorbent for the removal of estrogens: kinetic and thermodynamic studies

“…Nylon 6 is a general chemical material, consisting of amide groups which are separated by methylene sequences, where nonpolar interactions are expected between hydrophobic compounds and the methylene chains of Nylon 6. Our previous research, using the Nylon 6 electrospun nanofibers mat as solid-phase extraction (SPE) sorbent, has demonstrated the highly effective extraction nature of the Nylon 6 nanofibers mat for nonpolar and medium polarity EDCs, such as natural and synthetic estrogens [ 17 , 18 ], bisphenol A [ 19 ], and phthalate esters [ 20 , 21 ] in environmental water. It is indicated from the results of our work that the extremely large surface-to-volume ratio and numerous micropores make nanofibers mat a promising high-performance adsorbent material that can achieve a larger specific surface and more active sites for adsorption, compared with microscale adsorbents.…”