Determination of aluminum in environmental and biological samples by reversed-phase high-performance liquid chromatography via pre-column complexation with morin

Lian, Hong-zhen; Kang, Yufen; Arkin, Yasin; Bi, Shuping; Shao, Dalin; Chen, Yijun; Dai, Lemei; Tian, Lianhua

doi:10.1016/s0021-9673(03)00359-5

Cited by 36 publications

(15 citation statements)

References 14 publications

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“…The work of H. Lian et al indicated that the MorinAluminum complex was satisfactorily separated on a Spherisorb 18 ODS 2, 5 mm, 150x4.6 mm column using mobile phase as methanol-water (30:70) adjusted to pH 1.0 with perchloric acid [16]. Perchloric acid was chosen due to low complexation power to Al.…”

Section: Resultsmentioning

confidence: 99%

“…In chromatographic system dissociation, hydrolysis, ion or ligand exchange can make the separation difficult. The problem is concerned with the stability of the complexes (16,17). Therefore, in this study, the stability constants of the copper (II) and aluminium(III) complexes of quercetin were determined potentiometrically by using Calvin-Bjerrum and Irwing Rossotti methods (18,19).…”

Section: Introductionmentioning

confidence: 99%

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Kuersetinin Cu(II) ve Al(III) Komplekslerinin Potansiyometrik ve Kromatografik İncelenmesi

Yılmaz¹,

Pekin²

2017

Marmara Pharmaceutical Journal

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Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Kuersetinin Cu(II) ve Al(III) Komplekslerinin Potansiyometrik ve Kromatografik İncelenmesi

Yılmaz¹,

Pekin²

2017

Marmara Pharmaceutical Journal

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“…It was reported that the most probable stoichiometry of Al:morin is 1:2 in methanol and 1:1 in acidic media [29]. It was reported in literature to utilize the strong chelating power of flavonoids with Al 3+ to quantify flavonoids or aluminum with low detection limits based on fluorescence [30][31][32].…”

Section: Effect Of Morin Concentrationmentioning

confidence: 99%

Separation/Preconcentration Methods for the Determination of Aluminum in Dialysate Solution and Scalp Hair Samples of Kidney Failure Patients

Khan

Kazi

Baig

et al. 2011

Biol Trace Elem Res

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A new method is reported for the separation of aluminum ions (Al(3+)) from interfering cations in pharmaceutical and biological samples through solid-phase extraction (SPE) using 2-methyl-8-hydroxyquinoline (8-hydroxyquinaldine) on activated silica. While separated Al(3+) was preconcentrated by cloud point extraction (CPE) using 3,5,7,2'-4'-pentahydroxyflavone (morin) as complexing reagent, the resulting complex was entrapped in nonionic surfactant (Triton X-114) as prior step to its determination by spectrofluorimetry (SPF). The validity of separation/preconcentration of Al(3+) was checked by certified reference material of human hair and standard addition method. The chemical variables affecting the analytical performance of the separation/preconcentration methods were studied and optimized. The enrichment factor and detection limit of Al(3+) for the preconcentration of 10 ml of dialysate solution and acid-digested samples of scalp hair samples were found to be 25 and 0.34 μg/L, respectively. The relative standard deviation for six replicates of standard containing 20 μg/L of Al(3+) was <10%. In all DS, the concentration of Al was >10 μg/L. The level of Al in scalp hair samples of kidney failure patients was higher than healthy controls.

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“…Recently, high-performance liquid chromatography interfaced to flame atomic spectrometry (HPLC–FAAS) [10] and a post-column derivatization procedure with 4,5-dihydroxy-1,3 benzene disulfonic acid disodium salt [11] have been used to quantify aluminium fluoride complexes in groundwater samples. Several high-performance liquid chromatography methods have been reported for the analysis of aluminium in various matrixes (aqueous, serum and wine samples), the majority of which include pre-column derivatization with lumogallion [12–14], morin [15], quercetin [16], N - o -vanillidine-2-amino-p-cresol [17] and 8-hydroxyquinoline [18, 19]. Flow and sequential injection methods have been reported for the spectrofluorimetric determination of aluminium in pharmaceutical formulations using chromotropic acid as chromogenic reagent [20].…”

Section: Introductionmentioning

confidence: 99%

Pre-Column Derivatization HPLC Procedure for the Quantitation of Aluminium Chlorohydrate in Antiperspirant Creams Using Quercetin as Chromogenic Reagent

et al. 2014

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This article describes the development and validation of a selective high-performance liquid chromatography method that allows, after liquid–liquid extraction and pre-column derivatization reaction with quercetin, the quantification of aluminium chlorohydrate in antiperspirant creams. Chromatographic separation was achieved on an XTerra MS C18 analytical column (150 × 3.0 mm i.d., particle size 5 μm) using a mobile phase of acetonitrile:water (15:85, v/v) containing 0.08 % trifluoroacetic acid at a flow rate of 0.30 mL min−1. Ultraviolet spectrophotometric detection at 415 nm was used. The assay was linear over a concentration range of 3.7–30.6 μg mL−1 for aluminium with a limit of quantitation of 3.74 μg mL−1. Quality control samples (4.4, 17.1 and 30.6 μg mL−1) in five replicates from five different runs of analysis demonstrated intra-assay precision (% coefficient of variation <3.8 %), inter-assay precision (% coefficient of variation <5.4 %) and an overall accuracy (% recovery) between 96 and 101 %. The method was used to quantify aluminium in antiperspirant creams containing 11.0, 13.0 and 16.0 % (w/w) aluminium chlorohydrate, respectively.

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Determination of aluminum in environmental and biological samples by reversed-phase high-performance liquid chromatography via pre-column complexation with morin

Cited by 36 publications

References 14 publications

Kuersetinin Cu(II) ve Al(III) Komplekslerinin Potansiyometrik ve Kromatografik İncelenmesi

Kuersetinin Cu(II) ve Al(III) Komplekslerinin Potansiyometrik ve Kromatografik İncelenmesi

Separation/Preconcentration Methods for the Determination of Aluminum in Dialysate Solution and Scalp Hair Samples of Kidney Failure Patients

Pre-Column Derivatization HPLC Procedure for the Quantitation of Aluminium Chlorohydrate in Antiperspirant Creams Using Quercetin as Chromogenic Reagent

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