The level structure of the N = 82 nucleus 136 Xe was studied with the inelastic neutron scattering reaction followed by γ-ray detection. A number of the spins and parities were reassigned , and many level lifetimes were determined for the first time using the Doppler-shift attenuation method. New shell-model calculations were also performed using both the full Z = 50 − 82 model space, and a reduced model space including only the 1d 5/2 and 0g 7/2 orbitals. This new information characterizing 136 Xe was used to identify the seniority structure of the low-lying levels and to assign (π0g 7/2) 4 υ=0 , (π0g 7/2) 4 υ=2 , (π0g 7/2) 4 υ=4 , (π1d 5/2)(π0g 7/2) 3 υ=1 , and (π1d 5/2) 2 (π0g 7/2) 2 υ=0 configurations to describe all observed states below 2.8 MeV.