2023
DOI: 10.1016/j.fuproc.2023.107913
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Decarboxylative - Dimerization of levulinic acid using spent Li-ion battery electrode material with lithium nickel cobalt manganese oxide as a catalyst

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Cited by 3 publications
(3 citation statements)
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“…In this context, Amarasekara et al reported innovative approaches to enhance the value of biomass-derived compounds through conversion by recycled catalysts from spent LIBs [30][31][32]. The recycling of LIBs for reuse as catalysts involved a discharging and mechanical dismantling process (Figure 2a).…”
Section: Catalyst From Spent Lithium-ion Batteriesmentioning
confidence: 99%
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“…In this context, Amarasekara et al reported innovative approaches to enhance the value of biomass-derived compounds through conversion by recycled catalysts from spent LIBs [30][31][32]. The recycling of LIBs for reuse as catalysts involved a discharging and mechanical dismantling process (Figure 2a).…”
Section: Catalyst From Spent Lithium-ion Batteriesmentioning
confidence: 99%
“…Interfering organic residues, e.g., binders, were removed by pyrolyzing the cathode and anode black material at 600 • C. After grinding and sieving, the resulting powder of LiNi x Mn y Co z O 2 /C was used as a catalyst (Figure 2b). The authors demonstrated the practicability of this catalyst for the transformation of different biomass-derived substrates, namely the oxidation of cellulose-derived furans to their corresponding carboxylic acids [30], the oxidation of D-glucose to glycolic acid [31], and the decarboxylative dimerization of levulinic acid [32]. For example, the oxidation of furans, including furan-2-aldehyde, 5-hydroxymethyl furfural, and 5,5 ′ -[oxybis(methylene)]bis [2-furaldehyde], achieved moderate-to-high yields ranging from 82% to 97% depending on the substrate used.…”
Section: Catalyst From Spent Lithium-ion Batteriesmentioning
confidence: 99%
“…We have been studying the catalytic activities of the lithium nickel manganese cobalt oxide with the general formula Li a Ni b Mn c Co d O e derived from spent Li-ion battery waste for oxidation of sugars as well as biomass-derived furans for producing value-added products such as glycolic acid in recent years [33,34]. In addition, we have reported the use of lithium nickel manganese cobalt oxide as a catalyst for decarboxylative dimerization of levulinic acid in upgrading this biomass-derived carboxylic acid [35]. While attempting to oxidize glucose to gluconic acid using battery waste LiNMC/graphite catalyst, we have observed a facile oxidation of glucose to a mixture of carboxylic acids, including some hydroxy acids and effortless leaching of Li, Ni, Mn, and Co metal ions in LiB electrode coating material into aqueous medium under mild conditions [33].…”
Section: Introductionmentioning
confidence: 99%