ered the superconductivity phenomenon of magic angle of double-layer graphene, which opened a new chapter of research. Groundbreaking theoretical researches on graphene have emerged in a short period of more than ten years.Graphene is the hardest and thinnest material among 2D materials, [3] with very high light transmittance, high electron mobility, good thermal conductivity, and the ability to carry high current density. Based on these properties, it is widely used in flexible sensors, light-emitting devices, composite materials, energy, touch screens and high frequency electronics. [4][5][6][7][8] Therefore, graphene is regarded as a strategic emerging material in the 21st century. It is expected to become a landmark material in the era of human civilization after stone, bronze, steel, and silicon.According to the definition of International Organization Standardization (ISO), graphene can be monolayer, bilayer, multilayer (3-10 layers), or nanosheet (1-3 nanometers thick). As far as the raw materials, the quality of graphene produced in labs and factories varies. The ideal graphene is a perfect 2D honeycomb single crystal pure carbon material, while the actual graphene is a defective polycrystalline film or powder piled up by single crystal fragments. In 2018, Kauling et al. [9] tested and analyzed the product quality of sixty graphene manufacturers from the Americas, Europe, and Asia. The results show that the qualities of graphene products are far less than expected. Most companies only produce graphite microplatelets with very small particles rather than graphene. Thus, most of the potential application cannot be realized in these products.Graphene has gradually emerged as products in the market in recent years. Following the first application of graphene film in cellphone, the first 5th generation mobile communication technology tablet in China, was released in May 2020 with ultrathick 3D graphene cooling technology. Besides, the rapid spread of COVID-19 in 2020 led to the withdrawal of global medical resources, has inspired new application fields of graphene, such as graphene masks, [10] remote intelligent wearable devices, such as motion monitoring sensors, [11] and other graphene-based functional devices at microwave, terahertz, and optical frequencies. [12] Therefore, searching for the proper graphene-based industrial applications is a driving force for the benign development of the industry.In general, there is basically rare high-quality graphene that meets ISO standards in the market at present, which seriously Graphene, as an emerging 2D material, has been playing an important role in flexible electronics since its discovery in 2004. The representative fabrication methods of graphene include mechanical exfoliation, liquid-phase exfoliation, chemical vapor deposition, redox reaction, etc. Based on its excellent mechanical, electrical, thermo-acoustical, optical, and other properties, graphene has made a great progress in the development of mechanical sensors, microphone, sound source, electrophysio...