“…33−35,47−49 In the past several decades, diverse experimental methods have been proposed to synthesize size-dependent, carbon-supported, Ptbased alloy nanoparticle catalysts in a variety of shapes, such as rod, wire, polyhedron, dendrite, dimmer, belt, star, and cage. 11 These experimental strategies have included (1) controlling the size of Pt-based nanocatalysts within a small range of 3−5n m to yield a high electrochemical active area and catalytic activity, (2) controlling the shape of Pt-based catalysts to give more complex morphologies (e.g., a dendritic morphology), (3) obtaining high-index facets in nanocatalysts favoring high activity and stability for fuel cell applications, (4) designing controlled architectures (e.g., textured structure, such as core− shell, Pt skin, or Pt monolayer) for Pt-based catalysts, (5) developing new support materials with high conductivity, chemical stability, and surface area, 50,51 and (6) achieving a uniform distribution of Pt or Pt-alloy nanoparticles on advanced support materials with high conductivity.…”