of nitrate leaching. Nitrate can also be lost by denitrification in wet soils, which is also most likely to occur in Time of N fertilizer application to corn (Zea mays L.) and use of spring. Soils with subsurface drainage may be at higher a nitrification inhibitor are management strategies that can affect corn risk for nitrate leaching, but at lower risk for N loss due production and loss of NO 3 -N from the soil profile via subsurface, tile drainage. A field study was conducted from the fall of 1986 through to denitrification.
on a tile-drained Canisteo clay loam soil [fine-loamy, mixedApplication of N in the fall has advantages for both (calcareous), mesic Typic Endoaquolls] to determine the influence growers and the fertilizer industry. These economical of time of N application and nitrapyrin [2-chloro-6-(trichloromethyl) and logistical advantages include better distribution of pyridine] on yield of corn and soybean [Glycine max (L.) Merr.] labor and equipment demands, time savings during the in rotation and N uptake of corn. Four anhydrous ammonia (AA) busy spring planting season, lower N costs in some years, treatments [(fall without nitrapyrin (NP), fall with NP, spring preplant, and frequently more favorable soil conditions for field and split (40% preplant and 60% sidedress at V8 stage)] were repliwork (Bundy, 1986; Randall and Schmitt, 1998). Becated four times and applied at 150 kg N ha Ϫ1 (135 lb N acre Ϫ1 ) for cause of the risk of losing a portion of fall-applied N, corn each year. Fall applications occurred between 19 and 28 October recommendations for fall N usually specify use of amwhen soil temperatures generally were Յ10؇C. Seven-year average corn grain yields were least for fall N without NP (8.27 Mg ha Ϫ1 , 131 monium forms and delaying time of application until bu acre Ϫ1 ), intermediate for fall N with NP and spring N (8.72 Mg soil temperatures are Ͻ10ЊC ( Keeney, 1982). Compariha Ϫ1 , 139 bu acre Ϫ1 ), and greatest for the split N treatment (9.11 Mg sons of corn yield after fall or spring N application have ha Ϫ1 , 145 bu acre Ϫ1 ). Corn N uptake was not different among treatbeen variable. Fall application (mid-November) proments in drier years but was generally greatest for the spring and split duced lower corn grain yields than spring preplant or treatments in wet years. Apparent N recovery ranged from 31% for sidedress application regardless of N rate in Ontario fall N without NP to 44% for the split treatment. Economic return (Stevenson and Baldwin, 1969). The yield reduction asto fertilizer was greatest for the split treatment ($239.40 ha Ϫ1 yr Ϫ1 ) sociated with fall application was greater on clay soils and lowest for fall N without NP ($166.70 ha Ϫ1 yr Ϫ1 ). Application than on loam soils. Three-yr yield averages showed fall