Core-shell bimetallic Fe-Co MOFs to activated peroxymonosulfate for efficient degradation of 2-chlorophenol

Synthesis of bimetal MOFs for rapid removal of doxorubicin in water by advanced oxidation method

“…6d ), two peaks appear at 779.9 and 781.1 eV, indicating the presence of Co( ii ) and Co( iii ), respectively, on the surface of Co/Cu-MOFs. 47 After DOX degradation, the Co( ii ) in Co/Cu-MOFs is consumed to activate the autolysis of PMS and converted to Co( iii ) ( eqn (1) ). The Co( iii ) are re-converted to Co( ii ) by capturing electrons ( eqn (2) ), which inhibits the production of reactive oxygen species (ROS) and causes a decrease in catalyst activity.…”

Degradation of organic contaminants by peroxymonosulfate activated with zeolitic imidazolate framework-based catalysts: performances, mechanisms and stability

“…45,46 Gu et al prepared core–shell bimetallic MIL-101/ZIF-67 x with superior catalytic performance for the degradation of 2-chlorophenol (2-cp). 47 The past research studies on the activation of PMS for degradation of organic contaminants by pristine ZIFs are summarized in Table 1.…”

“…The recycling efficiency was slightly decreased after 3 cycles 41 47 The past research studies on the activation of PMS for degradation of organic contaminants by pristine ZIFs are summarized in Table 1.…”

Role of Interface of Metal–Organic Frameworks and Their Composites in Persulfate-Based Advanced Oxidation Process for Water Purification

“…Gu et al prepared a core–shell bimetallic MIL-101/ZIF-67 x (M/Z x ) consisting of an ordered ZIF-67 shell and the MIL-101 core . In the M/Z 2 /PMS system, the addition of Cl – significantly improved the removal of 2-chlorophenol (2-CP).…”

“…•− . 65,117 In some special cases, low content of NaHCO 3 (5 or 10 mM) exhibited slight inhibition of bisphenol F (BPF) degradation by the PMS/Fe 3 O 4 −PVP@ZIF-67 system (poly(vinylpyrrolidone), PVP). 106…”