Copper(I) and mercury(II) halide complexes of 1,2-bis(diphenylthioylphosphino)hydrazine

Ainscough, Eric W.; Brodie, Andrew M.; Derwahl, Andreas; Freeman, Graham H.; Otter, Carl A.

doi:10.1016/j.poly.2007.08.009

Cited by 7 publications

(2 citation statements)

References 23 publications

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“…41 Mercury halide complexes of 1,2-bis(diphenylthiophosphino)-hydrazine (L 5 ) have been synthesised and the products found to vary depending on the halide present. 42 Similar dimers are observed for mercury(II) halide complexes formed with the 4methoxybenzoylmethylenetriphenylphosphorane ligand, 43 while the first dinuclear complex of mercury containing formamidinate ligands, [Hg 2 (pmf) 2 X 2 ] (Hpmf = N,N 0 -bis(pyrimidine-2-yl)formamidine, X = Cl, Br, I), has also been prepared. 44 The mercury(II) complexes of sulfadiazine, sulfamerazine and sulfamethazine have also been probed.…”

Section: Mercurymentioning

confidence: 53%

Zinc, cadmium and mercury

West

2008

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

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This Chapter reviews the literature reported during 2007 on zinc, cadmium and mercury. The synthesis of novel compounds and complexes of these metals is reviewed and new observations and inferences are reported. Research highlights for each of the metals during the year are also given. HighlightsThe first structurally-characterised compound containing a Zn-Zr bond has been reported. 4 Three novel Schiff base cadmium(II) trimeric complexes have been prepared using symmetrical Schiff bases. 31 The first dinuclear mercury complex containing formamidinate ligands has been prepared.

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Section: Mercurymentioning

confidence: 53%

Zinc, cadmium and mercury

West

2008

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem.

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“…The solvents were purified and dried according to standard procedures. [15] The 2,2-dichloro-4,4,6,6-bis-[spiro(2 ,2 -dioxy-1 ,1 -biphenyl)]-cyclotriphosphazene (2Cl-CP) ligand was synthesized using reported procedures [16,17]. The Hexachlorocyclotriphosphazene was purified by sublimation at 80-90 • C (Sigma-Aldrich) and 2 ,2 -dioxy-1 ,1 -bisphenyl used without further purification (Sigma-Aldrich).…”

Section: Methodsmentioning

confidence: 99%

Synthesis of Pyridyloxycyclophosphazene and its Cu(I) Complex

Boncukçu

Elmalı

Demirhan

2013

Main Group Chemistry

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A new pyridyloxycyclophosphazene, called 2,2 -bis[2-oxy-6-methyl-pyridine]-4,4,6,6-bis[spiro(2 ,2"-dioxy-1,1biphenyl)]cyclotriphosphazane (BB-CP) has been synthesized from the reaction of 2,2-dichloro-4,4,6,6-bis[spiro(2',2"dioxybiphenyl)] cyclotriphosphazane (2Cl-CP) and 2-hydroxy-6-methylpyridine (HMP). The Cu(I) complex of this ligand has been prepared. The new ligand and Cu(I) complex were characterized by FT-IR, 1 H NMR, 31 P NMR, UV-vis, mass spectra, elemental and thermal analyses.

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