Abstract:High-speed coherent optical communication has been expanding to handle the ever-increasing data traffic, and the large modulation bandwidth of electro-optic (EO) polymer modulators has been especially appreciated. However, to be useful in optical communication, the EO polymer device should address several issues, such as thermal stability, photo-oxidation, and bias drift. In this work, as a part of the experiments to address these challenges, an EO polymer with a fluorinated polyimide backbone is utilized to c… Show more
“…Moreover, side chain polymer system retain its degree of freedom which eventually can enhance the poling competency to that of host-guest system. Most commonly used polymers in this system includes, the Vinyl based NLO polymers (polystyrene and polymethyl methacrylate) and NLO polymeric materials having elevated T g such as, polyurethane, polyimide, polyamide, polyester, polyether, and polyquinoline [47][48][49][50][51][52]. Previously a substantial literature regarding various side-chain NLO polymer categories have been documented [53][54][55][56][57][58][59][60][61][62][63].…”
The rocketed development concerning electro-optic polymers fundamentally motivated by its pragmatic application in envisioning second-order nonlinear optics and waveguiding are cardinal. Modern synthetic strategies consigned an outstanding optical quality amorphous polymers with enhanced properties. Documented data revealed a huge progress in understanding their implementation, however challenges still exist regarding their temporal stabilities etc. This review delivers a brief investigation of nonlinear optical (NLO) polymer materials demonstrated over previous decades. Besides, their categorical explanation along with their structural architecting via engineering polymeric backbone or functionalization of the molecular entities have been reviewed. Correspondingly, their temporal and thermal stabilities accompanied by NLO characteristics features are also discussed.
“…Moreover, side chain polymer system retain its degree of freedom which eventually can enhance the poling competency to that of host-guest system. Most commonly used polymers in this system includes, the Vinyl based NLO polymers (polystyrene and polymethyl methacrylate) and NLO polymeric materials having elevated T g such as, polyurethane, polyimide, polyamide, polyester, polyether, and polyquinoline [47][48][49][50][51][52]. Previously a substantial literature regarding various side-chain NLO polymer categories have been documented [53][54][55][56][57][58][59][60][61][62][63].…”
The rocketed development concerning electro-optic polymers fundamentally motivated by its pragmatic application in envisioning second-order nonlinear optics and waveguiding are cardinal. Modern synthetic strategies consigned an outstanding optical quality amorphous polymers with enhanced properties. Documented data revealed a huge progress in understanding their implementation, however challenges still exist regarding their temporal stabilities etc. This review delivers a brief investigation of nonlinear optical (NLO) polymer materials demonstrated over previous decades. Besides, their categorical explanation along with their structural architecting via engineering polymeric backbone or functionalization of the molecular entities have been reviewed. Correspondingly, their temporal and thermal stabilities accompanied by NLO characteristics features are also discussed.
Electro-optic (EO) modulators are typically made of inorganic materials such as lithium niobate; the replacement of these modulators with organic EO materials is a promising alternative due to their lower half-wave voltage (Vπ), ease of handling, and relatively low cost. We propose the design and fabrication of a push-pull polymer electro-optic modulator with voltage-length parameters (VπL) of 1.28 V·cm. The device uses a Mach–Zehnder structure and is made of a second-order nonlinear optical host-guest polymer composed of a CLD-1 chromophore and PMMA polymer. The experimental results show that the loss is 1.7 dB, Vπ drops to 1.6 V, and the modulation depth is 0.637 dB at 1550 nm. The results of a preliminary study show that the device is capable of efficiently detecting electrocardiogram (ECG) signals with performance on par with that of commercial ECG devices.
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