“…Nanoscale protuberances reduce the diameter of the eld emitter and thereby increase the eld enhancement, which will enhance electron eld emission. 26,41 Therefore, the decrease in the threshold eld of the W 18 O 49 nanowires was observed when the irradiation dose increased to 3.6 Â 10 15 phs cm À2 .…”
Section: Resultsmentioning
confidence: 92%
“…Excellent eld emission performance, including low turn-on eld, high current density, good stability, and high uniformity, has been reported for various one-dimensional tungsten oxide nanomaterials. [19][20][21][22][23][24][25][26][27][28][29] For example, in 2003, Li et al reported that W 18 O 49 nanotubes and nanowires can be prepared by heating tungsten foil under vacuum conditions and investigated their eld emission properties; the turn-on eld was only 2.6 MV m À1 . 19 Zhou et al used two thermal evaporation processes to grow W 18 O 49 nanotips; stable eld emission with uctuation of 2.0% at an emission current of 1200 mA over 13 hours and a low turn-on eld of 2.0 MV m À1 were obtained.…”
W18O49 nanowires were synthesized by thermal evaporation, and the effects of X-ray irradiation on their crystalline structure, chemical composition, and field emission properties were systematically investigated.
“…Nanoscale protuberances reduce the diameter of the eld emitter and thereby increase the eld enhancement, which will enhance electron eld emission. 26,41 Therefore, the decrease in the threshold eld of the W 18 O 49 nanowires was observed when the irradiation dose increased to 3.6 Â 10 15 phs cm À2 .…”
Section: Resultsmentioning
confidence: 92%
“…Excellent eld emission performance, including low turn-on eld, high current density, good stability, and high uniformity, has been reported for various one-dimensional tungsten oxide nanomaterials. [19][20][21][22][23][24][25][26][27][28][29] For example, in 2003, Li et al reported that W 18 O 49 nanotubes and nanowires can be prepared by heating tungsten foil under vacuum conditions and investigated their eld emission properties; the turn-on eld was only 2.6 MV m À1 . 19 Zhou et al used two thermal evaporation processes to grow W 18 O 49 nanotips; stable eld emission with uctuation of 2.0% at an emission current of 1200 mA over 13 hours and a low turn-on eld of 2.0 MV m À1 were obtained.…”
W18O49 nanowires were synthesized by thermal evaporation, and the effects of X-ray irradiation on their crystalline structure, chemical composition, and field emission properties were systematically investigated.
“…5(c) and (d)) reveal that the single crystal nature of the needle, and the d-spacing of 0.38 nm agrees well with the (010) plane of monoclinic W 18 O 49 . The needle-like microstructure is a typical morphology of the W 18 O 49 phase usually formed at high temperature [14,15]. In our work, the hot Cu melt (N 1300 K) produced from the aluminothermic reaction may dissolve minor oxygen.…”
“…1 Electron eld emission or cold cathode emission is a direct consequence of quantum tunnelling in which electrons from an emitting cathode pass to the anode by overcoming surface potential barrier in the presence of an externally applied electric eld. 1 Electron eld emission or cold cathode emission is a direct consequence of quantum tunnelling in which electrons from an emitting cathode pass to the anode by overcoming surface potential barrier in the presence of an externally applied electric eld.…”
In the present work, we report fabrication and field emission responses of 3D copper phthalocyanine (CuPc) nanotip arrays synthesized over nanotube walls by facile plasma treatment. Significant field emission enhancement is confirmed for a nanotip-nanotube hybrid system (turn-on field 4.2 V mm À1 @10 mA cm À2 ) as compared to pristine CuPc nanotubes (turn-on field 6.8 V mm À1 @10 mA cm À2 ). Root of the observed enhanced cold cathode emission performances is further probed by a finite element method based simulation protocol that computed local electric field distribution for a single tube without and with plasma etching in a manner parallel to the experimental setup. Our obtained results strongly suggest that CuPc nanotip-nanotube hybrid nanostructures are a major potential candidate as field emitters for vacuum nanoelectronics and cold cathode based emission display applications.
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