2016
DOI: 10.1021/acs.jafc.6b00680
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Constituents of Cypriol Oil (Cyperus scariosus R.Br.): N-Containing Molecules and Key Aroma Components

Abstract: Cypriol oil, the essential oil from Cyperus scariosus R.Br., has been investigated to reveal minor nitrogen-containing molecules and minor components responsible for the odor. A total of 21 nitrogenous components are reported, of which epi-guaipyridine (32 mg/kg), guaia-9,11-dienpyridine (9 mg/kg), and cananodine (10 mg/kg) were the most abundant. A new ketone, cyperen-8-one, with a significant woody, ambery odor could also be isolated and identified along with a novel lactone, cyperolactone, and an alcohol. R… Show more

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Cited by 18 publications
(30 citation statements)
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“…Despite its patchouli‐related name, (−)‐patchoulenone cannot be detected in PEO (Joulain, unpublished). However it does occur in Cyperus species . Consequently, the compounds that have been wrongly identified as "patchoulenone" and "isopatchoulenone" in PEO, still need to be correctly identified.…”
Section: Analytical Investigations Of Patchouli Essential Oilmentioning
confidence: 99%
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“…Despite its patchouli‐related name, (−)‐patchoulenone cannot be detected in PEO (Joulain, unpublished). However it does occur in Cyperus species . Consequently, the compounds that have been wrongly identified as "patchoulenone" and "isopatchoulenone" in PEO, still need to be correctly identified.…”
Section: Analytical Investigations Of Patchouli Essential Oilmentioning
confidence: 99%
“…In a review of N‐compounds in essential oils, Maurer cited the original paper by Büchi and consequently drew the epi isomer . The 1 H NMR data from van der Gen was insufficient to make an unambiguous identification but recently the structure was definitely established as 70 . Although guaiol pyridine or epicananodine 117 has been tentatively identified by NMR, its possible formation as an artifact by hydration of 70 (or even from patchouli pyridine 69 ) during the isolation procedure involving strong acid treatment, should not be ruled out.…”
Section: Analytical Investigations Of Patchouli Essential Oilmentioning
confidence: 99%
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“…The antioxidant activity of T. flousiana essential oil was measured in terms of radical scavenging activity, using the stable radical DPPH (Sigma-Aldrich, Darmstadt, Germany) [48]. A reaction mixture of 1 mL of a hexane solution of the essential oil with different concentrations (5,10,20,40, and 80 µg/mL) and equal volume of the methanolic solution of 0.3 mM DPPH was prepared, mixed well and incubated under dark condition for 15 min at room temperature. Ascorbic acid (5,10,20,40, and 80 µg/mL) was used as the reference.…”
Section: Determination Of Antioxidant Activitymentioning
confidence: 99%
“…11,12 Cananodine was also recently isolated from Cyperus scariosus . 13 Most importantly, cananodine ( 1 ) has activity against both the Hep G 2 and Hep 2,2,15 hepatocarcinoma cell lines, with IC 50 values of 0.22 and 3.8 μg/mL, respectively. 9 This compares favorably to the in vitro activity of sorafenib against Hep G 2 of 2.0 μg/mL.…”
mentioning
confidence: 99%