1989
DOI: 10.1039/f19898501531
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Conductance studies of alkali-metal chlorides and bromides in 2-methoxyethanol at 25 °C

Abstract: The conductances of a number of alkali-metal chlorides and bromides, MX(M+ = Li, Na, K, Rb, Cs and X-= C1, Br) have been measured in 2-methoxyethanol (ME) at 25 "C and the data have been analysed by the 1978 Fuoss Conductance equation in terms of the limiting molar conductance AO, the association constant, KA and the association distance, R.Single ion conductivities have been determined using Bu,NBPh, and Bu,NBBu, as reference electrolytes. Strong association was found for all these salts in ME and the limitin… Show more

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Cited by 19 publications
(9 citation statements)
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“…Alkali metal chlorides (Fluka) were of purum or puriss grade and purified by us as described earlier. , …”
Section: Methodsmentioning
confidence: 99%
“…Alkali metal chlorides (Fluka) were of purum or puriss grade and purified by us as described earlier. , …”
Section: Methodsmentioning
confidence: 99%
“…Recently, we have initiated a program to study Li + ion solvation in different nonaqueous solvents from conductometric, viscometric, and laser Raman spectroscopic measurements. The study has now been extended to 1,2-dimethoxyethane (DME), a solvent particularly relevant for battery construction using lithium electrodes.…”
Section: Introductionmentioning
confidence: 99%
“…It is an ether alcohol showing physicochemical characteristics midway between protic and dipolar aprotic solvents. As a result, it has attracted much attention as a solvent in electrochemical studies (Nandi et al, 1989; Franchini et al, 1986Franchini et al, , 1989Franchini et al, , 1990. Excess thermodynamic properties of the binary mixtures of 2-methoxyethanol have been reported earlier (Chandak et al, 1977;Marchetti et al, 1991).…”
mentioning
confidence: 99%