Complexes of rhodium(III) and iridium(III) with the mono-oximes of 1,2-naphthoquinone: X-ray crystal structure of pyridinium trichloro(1,2-naphthoquinone 1-oximato)(pyridine)iridate(III)

Charalambous, J.; Henrick, Kim; Musa, Yusuf; Rees, R.G.; Whiteley, Robert N.

doi:10.1016/s0277-5387(00)80918-3

Cited by 14 publications

(1 citation statement)

References 10 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Thus, A8 is referred to as a 1-nitroso-2-naphthol (or 1,2-naphthoquinone-1-oxime) complex, and A9 is the related 2-nitroso-1-naphthol complex. Several examples for A8, where the metal is Ru [1.22-1.28 Å], 184,216 Ir [1.274 Å], 217 or Cu [1.257-1.287 Å], 218,219 are known as are structures for A9, where the metal is Ru [1.19-1.26 Å] 216 or Cu [1.262-1.266 Å]. 220 Many metal-RNO complexes containing the violurato A10 and the uracil A11 frameworks are known.…”

Section: Spectroscopy and Structurementioning

confidence: 99%

Interactions of Organic Nitroso Compounds with Metals

et al. 2002

View full text Add to dashboard Cite

show abstract

Section: Spectroscopy and Structurementioning

confidence: 99%

Interactions of Organic Nitroso Compounds with Metals

et al. 2002

View full text Add to dashboard Cite

show abstract

Synthesis, Characterisation and Electrochemical Behaviour of Rhodium(III) Complexes Containing 1,2-Naphthoquinone-2-oxime and Formation of Imine Complexes through N−O Bond Cleavage

Liu

Wong

2001

Eur. J. Inorg. Chem.

View full text Add to dashboard Cite

The new rhodium(III) complexes [Rh(η2‐nqo)L2Cl2] (1a−1d) and [Rh(η2‐nqo)2LCl] (2b−2d) [1a, L = PPh3; 1b,2b, L = pyridine (py); 1c,2c, L = 4‐phenylpyridine (ppy); 1d,2d, L = 4‐acetylpyridine (apy)] have been prepared by treatment of the reaction mixture of RhCl3·3H2O and 1,2‐naphthoquinone‐2‐oxime (nqo) in ethanol by P or N donor ligands. Cyclic voltammetric studies show that the new complexes display an irreversible metal‐localised two‐electron reduction from RhIII to RhI, accompanied by the loss of the chloride ligands. The 1,2‐naphthoquinone‐2‐imine (nqi) complexes [Rh(η2‐nqo)(η2‐nqi)Cl2]·L (3b−3d) (3b, L = py; 3c, L = ppy; 3d, L = apy), [Rh(η2‐nqo)(η2‐nqi)Cl2] (4) and [Rh(η2‐nqo)2(nqi)Cl] (5) were obtained by deoxygenation of the oxime group in which N−O bond cleavage is observed. The molecular structures of 1a, 2b, 4 and 5 were established by single crystal X‐ray analyses.

show abstract

Synthesis, Structure and Reactions of Organometallic Derivatives of Oximes

Абеле

Lukevics

2010

Patai's Chemistry of Functional Groups

View full text Add to dashboard Cite

Organometallic derivatives of oximes were reviewed. These derivatives were selected and presented according to the place of the metal in the periodic table. Formation and reactions of disalts of oximes of type RC(CHMR′)=NOM (R, R′ = H, alkyl, aryl) and monosalts of oximes of type RC(CHMR′)=NOR″ (R″ = alkyl, aryl, M = alkali metal) were presented. Synthesis and reactions of silicon, germanium, tin, phosphorus containing oximes were included too. Beside this, oxime metal derivatives (for example, oxime palladacycles) as valuable catalysts in organic synthesis were described. In addition, oxime metal complexes exhibit wide spectrum of biological activity. Using of technetium‐99m hexamethylpropyleneamineoxime (Ceretec TM ) and related oxime complexes in diagnosis was described. Silicon and tin oxime complexes as excellent agrochemical agents were presented. Some cobalt, platinium and silicon containing oxime ethers exhibit high antitumor and cytotoxic activity and will be perspective targets for the further investigations. Introduction Synthesis, Structure and Reactions of Organometallic Derivatives of Oximes Conclusions

show abstract

Complexes of rhodium(III) and iridium(III) with the mono-oximes of 1,2-naphthoquinone: X-ray crystal structure of pyridinium trichloro(1,2-naphthoquinone 1-oximato)(pyridine)iridate(III)

Cited by 14 publications

References 10 publications

Interactions of Organic Nitroso Compounds with Metals

Interactions of Organic Nitroso Compounds with Metals

Synthesis, Characterisation and Electrochemical Behaviour of Rhodium(III) Complexes Containing 1,2-Naphthoquinone-2-oxime and Formation of Imine Complexes through N−O Bond Cleavage

Synthesis, Structure and Reactions of Organometallic Derivatives of Oximes

Contact Info

Product

Resources

About