2002
DOI: 10.1021/cr0000731
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Abstract: a Determined by microwave spectroscopy. b Determined by electron diffraction. c Data obtained from the Cambridge Structural Database. d This value was constrained. e Data for second molecule. f Data for disordered (minor) component.

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Cited by 237 publications
(265 citation statements)
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References 503 publications
(924 reference statements)
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“…39 The reaction was conducted with nitrosobenzene and diene having an alcohol group in the presence of stoichiometric amount of tert-butyl tartarate to give the corresponding adduct with complete regioselectivity and 92% ee. Key to the success is coordination of a hydroxy group of a diene to obtain a high enantioselectivity.…”
Section: Enantioselective Nitroso Hetero-diels-alder Reactionmentioning
confidence: 99%
“…39 The reaction was conducted with nitrosobenzene and diene having an alcohol group in the presence of stoichiometric amount of tert-butyl tartarate to give the corresponding adduct with complete regioselectivity and 92% ee. Key to the success is coordination of a hydroxy group of a diene to obtain a high enantioselectivity.…”
Section: Enantioselective Nitroso Hetero-diels-alder Reactionmentioning
confidence: 99%
“…Within the fingerprint area (wavenum- This only small decrease in wavenumbers lies in the expected range for σ -N coordination of C-nitroso compounds [9,47]. On account of the intense red color of the products in solution, UV/Vis spectra of 5a, 5b and 6a in dichloromethane were recorded ( Table 1).…”
Section: Resultsmentioning
confidence: 97%
“…Current reviews show the constant interest in this field of research during the last decades [7]. Not only due to its rich coordination chemistry with eleven different main coordination modes to metal centers [8,9], the family of C-nitroso compounds has been investigated extensively. Also the possible applications in organic synthesis [10], for example the nitroso ene [11] or nitroso Diels-Alder reaction [12 -14] attracted attention.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…Reviews and articles on individual classes of ligands that encompass metals across several groups include those on N-heterocyclic carbenes 5, 6 and related triazolium 7 and anionic borane N-heterocyclic carbene derivatives, 8 β-diketiminato metal complexes, 9 NO 10 and organonitroso complexes, 11 high oxidation state multiple metal-carbon bonds, 12 and the synthesis and catalytic application of metal carbonyl cations. 13 A personal perspective of a half-century of nonclassical organometallic chemistry 14 has also been published.…”
Section: Introductionmentioning
confidence: 99%