Combination effect of melamine polyphosphate and graphene on flame retardant properties of poly(vinyl alcohol)

Huang, Guobo; Liang, Huading; Wang, Yong; Wang, Xu; Gao, Jianrong; Fei, Zhengdong

doi:10.1016/j.matchemphys.2011.11.064

Cited by 114 publications

(60 citation statements)

References 35 publications

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“…For PVA, the flame retardancy of GNPs surpassed that of MMT and MWNTs [190]. GNPs also showed good flame retardant effects when using together with IFR formulations [191,192]. Exfoliated graphite nanoplatelets (xGnPs) were used to improve the flame resistant performance of glass fiber-reinforced polyester composite along with APP [193].…”

Section: Table 10mentioning

confidence: 99%

Intumescence: Tradition versus novelty. A comprehensive review

Alongi

Han

Bourbigot³

2015

Progress in Polymer Science

446

295

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Section: Table 10mentioning

confidence: 99%

Intumescence: Tradition versus novelty. A comprehensive review

Alongi

Han

Bourbigot³

2015

Progress in Polymer Science

446

295

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“…To solve the abovementioned problems, many researchers have made significant efforts to use graphene as an adjuvant in combination with other conventional flame retardants such as intumescent flame retardants and aluminium hydroxide [46][47][48][49][50][51], melamine polyphosphate [52], carbon black [53], layered double hydroxides (LDHs) [54], brominated polystyrene and antimony trioxide (Sb 2 O 3 ) [55], and aluminium hypophosphite [56]. As shown in Fig.…”

Section: Conventional Flame Retardants-graphene Blending Flame Retardantmentioning

confidence: 99%

Graphene-based flame retardants: a review

Sang

et al. 2016

J Mater Sci

185

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Graphene and its derivatives are potential flame retardant materials with good flame retardant performance; in particular, graphene as an adjuvant in combination with inorganic nanomaterials may be a promising candidate of flame retardant. This review describes the flame retardant mechanism, the development trend, and the classification of graphene-based flame retardants. It points out that graphene has attracted intensive interests in the fields of electronics, energy, and information, due to its excellent properties such as high thermal conductivity, good electron transport ability, and large specific surface area. In the meantime, graphene can change the pyrolysis as well as the thermal conductivity, heat absorption, viscosity and dripping of polymer during the combustion process. In other words, graphene can improve the thermal stability of polymer and delay its ignition, and it can also inhibit fire from spreading and reduce heat release rate.

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“…The results of TGA reveal the positive influence of GNPs on the thermal stability of the composites. The reason could be conducted as follows: (i) the GNPs formed a compact carbon layer during heating, which acted a protective barrier to block the transfer of mass and heat [19][20][21]; (ii) due to the functional groups on the surface of GNPs, the interfacial adhesion between GNPs and MVQ generated and restricted the thermal motion of MVQ macromolecules [22]. And the interfacial adhesion mainly contained van der Waals' interactions and covalent bonds taking place at the interfaces.…”

Section: Thermal Properties Of Gnp/mvq Compositesmentioning

confidence: 99%