ChemInform Abstract: SUBSTITUENT EFFECT OF THE PHOSPHINO AND THE PHOSPHINYL GROUPS ON THE REACTIVITY OF AROMATIC COMPOUNDS. I. KINETIC INVESTIGATION OF THE SUBSTITUENT EFFECT
Abstract:Als experimentelle Grundlage für die Diskussion der Substituenteneffekte der Phosphino‐ und der Phosphinylgruppe unter Zuhilfenahme der Molekülorbital‐Theorie werden die Esterverseifung der Benzoesäureester (I) zu (II), die nukleophile aromatische Substitution der Fluorbenzole (III) zu (IV), die nukleophile aliphatische Substitution der Benzylchloride (V) zu (VI) und die Methanolyse der α‐Chloräthylbenzole (VII) zu (VIII) kinetisch untersucht.
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