Selective epitaxial growth of Si in deep trenches is characterized using a combination of deep level transient spectroscopy, scanning electron microscopy, defect etch, and current-voltage measurements. The experimental results indicate that the majority of the defects observed are located near the sidewalls of the deep trenches. In the areas far away from the sidewalls, the deep level defect concentration is measured to be less than 10 ~~ cm 3. The success of this effort could lead to an integrated structure of the Si photodiode and the Si VLSI.