Chemical-enzymatic fractionation to unlock the potential of biomass-derived carbon materials for sodium ion batteries

Feng, Yiming; Tao, Lei; He, Yanhong; Jin, Qing; Kuai, Chunguang; Zheng, Yunwu; Li, Mengqiao; Hou, Qingping; Zheng, Zhifeng; Lin, Feng; Huang, Haibo

doi:10.1039/c9ta09124f

Cited by 48 publications

(55 citation statements)

References 72 publications

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“…[151,152] M a X b materials provide the required "vacancies" for the insertion of Li + in the process of discharging. [153] The valence of a certain element in M a X b can be changed due to the Li + insertion and extraction process, while the structural [48,[78][79][80][81][82][83][84] The performance improvement diagrams of BDC-based materials in b) LIBs, [79,80,[85][86][87][88][89][90][91][92][93][94][95] c) SIBs, [8,81,[96][97][98][99][100][101][102][103] and d) KIBs [104][105][106][107][108][109][110][111][112][113] in recent years. e) Comparison of LIBs, SIBs, and KIBs.…”

Section: Alloying Reaction Electrode Materialsmentioning

confidence: 99%

“…[48,[78][79][80][81][82][83][84] Many studies have been reported by using BDC as an important part of batteries. [50][51][52][53][54][55][56][57][58][59][60] To better understand the research progress of BDC, we summarized the performance improvement diagrams of BDC-based materials in LIBs (Figure 1b), [79,80,[85][86][87][88][89][90][91][92][93][94][95] SIBs (Figure 1c) [8,81,[96][97][98][99][100][101][102][103] and KIBs (Figure 1d) [104][105][106][107][108]…”

Section: Introductionmentioning

confidence: 99%

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Biomass‐Derived Carbon for High‐Performance Batteries: From Structure to Properties

Sun

Shi

Yang

et al. 2022

Adv Funct Materials

105

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Owing to the sustainability, environmental friendliness, and structural diversity of biomass-derived materials, extensive efforts have been devoted to use them as energy storage materials in high-energy rechargeable batteries. A timely and comprehensive review from the structures to mechanisms will significantly widen this research field. Here, it starts with the operation mechanism of batteries, and it aims to summarize the latest advances for biomass-derived carbon to achieve high-energy battery materials, including activation carbon methods and the structural classification of biomass-derived carbon materials from zero dimension, one dimension, two dimension, and three dimension. Each strategy starts with carefully selected examples and then moves to illustrate the underlying transport mechanism of electrons in the structure. In the end, challenges, strategies, and outlooks are pointed out for the future development of biomass-derived carbon materials. Overall, this review will help researchers choose appropriate strategies to design biomass-derived carbon materials, thereby promoting the application of biomass materials in battery design.

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Section: Alloying Reaction Electrode Materialsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Biomass‐Derived Carbon for High‐Performance Batteries: From Structure to Properties

Sun

Shi

Yang

et al. 2022

Adv Funct Materials

105

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“…[21] More recently,F eng et al proposed ap rocess to produce high-performance HC materials for SIBs by manipulating the componentsi nd ifferent plant biomasses. [150] They removed non-lignocellulose (such as proteins, minerals, and starch) andh emicellulose from three type of biomass, namely, brewer's spent grain, grape pomace, and walnuts hells, throughac hemical-enzymatic fractionation process in acid so-lution to product acidd etergent fibers (ADFs). The HCs derived from these ADFs all displayed excellent electrochemical properties.T he simultaneous absence of non-lignocellulose and hemicellulose led to expanded (002)i nterlayer spacing, which enhanced the specificc apacity remarkably.T his study provides afeasible methodt opreparebiomass carbon with high consistency.…”

Section: Challenges For Practical Applicationsmentioning

confidence: 99%

“…More recently, Feng et al. proposed a process to produce high‐performance HC materials for SIBs by manipulating the components in different plant biomasses . They removed non‐lignocellulose (such as proteins, minerals, and starch) and hemicellulose from three type of biomass, namely, brewer's spent grain, grape pomace, and walnut shells, through a chemical–enzymatic fractionation process in acid solution to product acid detergent fibers (ADFs).…”

Section: Challenges For Practical Applicationsmentioning

confidence: 99%

Biomass‐Derived Carbons for Sodium‐Ion Batteries and Sodium‐Ion Capacitors

et al. 2020

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In the past decade, the rapid development of portable electronic devices, electric vehicles, and electrical devices has stimulated extensive interest in fundamental research and the commercialization of electrochemical energy‐storage systems. Biomass‐derived carbon has garnered significant research attention as an efficient, inexpensive, and eco‐friendly active material for energy‐storage systems. Therefore, high‐performance carbonaceous materials, derived from renewable sources, have been utilized as electrode materials in sodium‐ion batteries and sodium‐ion capacitors. Herein, the charge‐storage mechanism and utilization of biomass‐derived carbon for sodium storage in batteries and capacitors are summarized. In particular, the structure–performance relationship of biomass‐derived carbon for sodium storage in the form of batteries and capacitors is discussed. Despite the fact that further research is required to optimize the process and application of biomass‐derived carbon in energy‐storage devices, the current review demonstrates the potential of carbonaceous materials for next‐generation sodium‐related energy‐storage applications.

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“…It's clearly seen from XPS survey spectrum that the sample contains four elements of C, Fe, Co, and Se (Figure S1). In the high‐resolution C 1s spectrum (Figure 4a), the peaks at 283.8 and 284.8 eV are indexed to the bonding energies of C−C and C−O, respectively [32] . In the XPS spectrum of Fe 2p (Figure 4b), the peaks at 706.8 and 719.3 eV are assigned to Fe 2p 3/2 and Fe 2p 1/2 spin orbits, respectively [33] .…”

Section: Resultsmentioning

confidence: 99%

Graphene Aerogel Supported Fe−Co Selenide Nanocubes as Binder‐Free Anodes for Lithium‐Ion Batteries

Wang

Zhou

Xiao

et al. 2021

Zeitschrift anorg allge chemie

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Metal selenides as anode materials of lithium‐ion batteries (LIBs) has received considerable attention recently. In order to boost the electronic conductivity and alleviate the volume change of electrode materials upon the cycles, a facile strategy is employed in this work, where Prussian blue analogue (PBA) nanocubes are encapsulated into three‐dimensional (3D) network of graphene aerogel (GA), followed by a high‐temperature selenization treatment to isolate the composite of FeCoSe2@GA. The composite can be directly employed as free‐standing anode materials of LIBs. Studies reveal that the FeCoSe2@GA electrode demonstrates an intriguing cycle stability and rate capability with a specific capacity of ∼500 mAh g−1 at 100 mA g−1 after 100 cycles. The outstanding lithium‐storage properties can be attributed to the 3D porous feature as well as the strong confinement effect of GA for FeCoSe2 particles, which provides a large number of ion‐exchange channels, and prevents the severe agglomeration and large volume expansion of active particles during the charge/discharge process.

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Chemical-enzymatic fractionation to unlock the potential of biomass-derived carbon materials for sodium ion batteries

Abstract: Plant biomass, the most abundant and sustainable carbon source, offers a rich chemical space to design hard carbons for sodium ion batteries.

Cited by 48 publications

References 72 publications

Biomass‐Derived Carbon for High‐Performance Batteries: From Structure to Properties

Biomass‐Derived Carbon for High‐Performance Batteries: From Structure to Properties

Biomass‐Derived Carbons for Sodium‐Ion Batteries and Sodium‐Ion Capacitors

Graphene Aerogel Supported Fe−Co Selenide Nanocubes as Binder‐Free Anodes for Lithium‐Ion Batteries

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