Measurements of the 55 Fe isotope emission spectra and the photosensitivity of CdTe detectors with a Schottky diode, and also the temperature dependence of the resistivity of a CdTe crystal ((2-3) × 10 9 Ω cm at 300 K) have been used to determine the concentration of uncompensated donors (1-3) × 10 12 cm -3 . Similar measurements performed for Cd 0.9 Zn 0.1 Te crystals with the resistivity (3-5) × 10 10 Ω cm at 300 K have shown that the concentration of uncompensated donors in this case is lower by approximately four orders of magnitude. The results of calculations show that, due to such a significant decrease in the con centration of uncompensated donors, the efficiency of X and γ ray radiation detection in the photon energy range 59 to 662 keV can decrease by one-three orders of magnitude (depending on the photon energy and the lifetime of charge carriers in the space charge region). The results obtained account for the apparent poor detecting properties of the Cd 0.9 Zn 0.1 Te detectors.