Characterisation of oxide films produced by plasma electrolytic oxidation of a Ti–6Al–4V alloy

Yerokhin, Aleksey; Nie, Xueyuan; Leyland, A.; Matthews, A.

doi:10.1016/s0257-8972(00)00719-2

Cited by 613 publications

(307 citation statements)

References 12 publications

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“…Also, it has exhibited excellent corrosion protection in simulated physiological solutions [20]. Other studies have reported the presence of titanium dioxide in rutile phase in similar coatings, this phase is desirable for its stability and corrosive properties [23,24]. However, the samples analyzed did not present this phase possibly for the short time of heat treatment employed.…”

Section: Xrdmentioning

confidence: 96%

“…Analyzing the diffraction pattern semi-crystalline structures with silicon incorporation in the coatings were identified, those affect the rate of bone growth in the early stages of bone formation and increase the proliferation and gene expression of osteoblasts, exhibiting anticorrosive properties [14]. Furthermore, the formation of titanium dioxide in anatase phase was observed, this phase is the most commonly formed in titanium oxidation processes [23]. Anatase is a desirable phase for ions incorporation in the coating, due to the capacity to absorb OH -and PO 4 3-groups that enhance the deposition of calcium and phosphorus [14].…”

Section: Xrdmentioning

confidence: 99%

“…It is a model composite of an oxide in a double layer, wherein the first layer corresponds to a porous outer layer or coating and the second layer to an inner barrier that represents the substrate, previously described in Bode diagrams and reported by other researchers [23,24].…”

Section: Figure 3 Bode Diagrams Coatings Obtained By Peomentioning

confidence: 99%

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EIS, Mott Schottky and EFM analysis of the electrochemical stability and dielectric properties of Ca-P-Ag and Ca-P-Si-Ag coatings obtained by plasma electrolytic oxidation in Ti6Al4V

Leal-Marin

Estupiñán-Duran

2017

Rev. Fac. Ing. Univ. Antioquia

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Ti6Al4V ELI (ASTM F136) alloy is one of the most used alloys in devices for osteosynthesis and joint replacement. However, the properties of this alloy can be improved regarding biocompatibility and the osteointegration with the bone tissue through coatings. The aim of this study was the evaluation of the electrochemical behavior of a coating obtained by plasma electrolytic oxidation on Ti6Al4V ELI, using electrolyte solutions enriched with PO 4 2-, Ca +2, Si +4 ions and various concentrations of Ag +1. The coatings were characterized by electrochemical impedance spectroscopy (EIS) and Mott-Schottky (M-S) in a three-electrode cell with a simulated physiological solution. The electrochemical behavior was compared with electrostatic force microscopy (EFM). The EIS results showed improved stability properties in corrosion for Ca-P-Ag coatings, compared with Ca-P-Si-Ag. Nyquist and Bode Spectra showed relaxations related to charge transference to the double electrochemical layer and the reflex of the microstructural changes and conductivity of the coating given by its composition. According to with M-S results, all the samples showed an n-type conductivity increased with silver inclusion. The potential, the phase, and amplitude of the coatings with silver inclusion compared to uncoated Ti6Al4V were observed by EFM. RESUMEN:El Ti6Al4V ELI (ASTM F136) es una de las aleaciones más empleadas en dispositivos de osteosíntesis y reemplazo articular. Sin embargo, las propiedades de esta aleación pueden ser mejoradas respecto a su biocompatibilidad y osteointegración con el tejido óseo a través de recubrimientos. El objetivo de este trabajo fue evaluar el comportamiento electroquímico de un recubrimiento obtenido por oxidación por plasma electrolítico sobre Ti6Al4V ELI empleando soluciones electrolíticas enriquecidas con iones de PO 4 2-, Ca +2 , Si +4 y varias concentraciones de Ag +1. Los recubrimientos se caracterizaron mediante espectroscopia de impedancia electroquímica (EIS) y Mott-Schottky (M-S) en una celda de tres electrodos con una solución fisiológica simulada. El comportamiento electroquímico se contrastó con microscopía de fuerza electrostática (EFM), donde se analizó el potencial eléctrico del recubrimiento. Los resultados de EIS mostraron mejores propiedades de estabilidad frente a la corrosión en los sustratos recubiertos con Ca-P-Ag, comparados con los recubiertos con Ca-P-Si-Ag. Los espectros de Nyquist y Bode mostraron relajaciones relacionadas con la transferencia de carga hacia la doble capa electroquímica como reflejo de los cambios microestructurales y de conductividad de los recubrimientos, dada por la presencia particular en cada caso, de los elementos contenidos en estos. De acuerdo con los resultados de M-S, todas las muestras ensayadas presentaron un comportamiento con dopado tipo n, cuya conductividad incrementó con la inclusión de plata. Mediante EFM se observaron mayores contrastes en el potencial, fase y la amplitud de los recubrimientos con mayor cantidad de plata respecto al Ti6Al...

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Section: Xrdmentioning

confidence: 96%

Section: Xrdmentioning

confidence: 99%

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EIS, Mott Schottky and EFM analysis of the electrochemical stability and dielectric properties of Ca-P-Ag and Ca-P-Si-Ag coatings obtained by plasma electrolytic oxidation in Ti6Al4V

Leal-Marin

Estupiñán-Duran

2017

Rev. Fac. Ing. Univ. Antioquia

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“…Also, the high thermal energy from the micro-arcs can produce ceramic coatings with complex structures. This method has been successfully used to produce ceramic coatings on light weight metals such as Ti, Al, Nb, Ta and Mg 47 . Recent studies have shown that HA can be produced by PEO of titanium and its alloys.…”

Section: Introductionmentioning

confidence: 99%

Mg-Containing Hydroxyapatite Coatings Produced by Plasma Electrolytic Oxidation of Titanium

et al. 2017

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Plasma Electrolytic Oxidation (PEO) is promising for the processing of biomaterials because it enables the production of surfaces with adjustable composition and structure. In this work, aimed at the improvement of the bioactivity of titanium, PEO has been used to grow calcium phosphide coatings on titanium substrates. The effects of the addition of magnesium acetate to the electrolytes on the composition of the coatings produced during 120 s on Ti disks using bipolar voltage pulses and solutions of calcium and magnesium acetates and sodium glycerophosphate as electrolytes have been studied. Scanning electron microscopy, X-ray energy dispersive spectroscopy, Rutherford backscattering spectroscopy, X-ray diffractometry with Rietveld refinement and profilometry were used to characterize the modified samples. Coatings composed of nearly 50 % of Mg-doped hydroxyapatite have been produced. In certain conditions up to 4% Mg can be incorporated into the coating without any observable significant structural modifications of the hydroxyapatite.

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“…5) Plasma electrolytic oxidation (PEO) has recently attracted attention to form ceramic-like coatings on aluminum, magnesium and titanium for corrosion and wear resistance. [6][7][8] Spark micro-discharge in PEO process modifies the structure, composition and morphology of the oxide layer; a thick, highly crystalline and melt-quenched high temperature oxide coating is formed by this process. Although the oxide is exposed locally and instantaneously at extremely high temperatures (10 3 -10 4 K), 6) the metal substrate should be kept at low temperatures, not causing mechanical damage.…”

Section: Introductionmentioning

confidence: 99%

Influence of Phosphate Concentration on Plasma Electrolytic Oxidation of AZ80 Magnesium Alloy in Alkaline Aluminate Solution

2010

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Plasma electrolytic oxidation of AZ80 magnesium alloy in alkaline aluminate electrolytes develops MgAl 2 O 4 -based highly crystalline oxide coatings with the morphology changing largely with phosphate concentration in electrolyte. The thickness of the coatings increases with phosphate concentration from 5 mm in phosphate-free electrolyte to $70 mm in the electrolyte containing 0.1 molÁdm À3 phosphate after anodizing for 900 s. The formation of the latter thick coating is associated with intense sparking during anodizing. The thick coatings formed in the electrolytes containing 0.075 and 0.1 molÁdm À3 phosphate are highly cracked. In contrast, the coating formed in the electrolyte containing 0.05 molÁdm À3 phosphate is relatively uniform, showing the highest corrosion protection in 0.5 molÁdm À3 NaCl solution. The coatings consist of two layers, comprising an outer thick layer with high concentration of aluminum and an inner thin magnesium-rich layer.

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Characterisation of oxide films produced by plasma electrolytic oxidation of a Ti–6Al–4V alloy

Cited by 613 publications

References 12 publications

EIS, Mott Schottky and EFM analysis of the electrochemical stability and dielectric properties of Ca-P-Ag and Ca-P-Si-Ag coatings obtained by plasma electrolytic oxidation in Ti6Al4V

EIS, Mott Schottky and EFM analysis of the electrochemical stability and dielectric properties of Ca-P-Ag and Ca-P-Si-Ag coatings obtained by plasma electrolytic oxidation in Ti6Al4V

Mg-Containing Hydroxyapatite Coatings Produced by Plasma Electrolytic Oxidation of Titanium

Influence of Phosphate Concentration on Plasma Electrolytic Oxidation of AZ80 Magnesium Alloy in Alkaline Aluminate Solution

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