Four oils [triolein, trilinolein, oleic acid-esterified propoxylated glycerol (EPG-08 oleate), and linoleic acid-esterified propoxylated glycerol (EPG-08 linoleate)], each without added antioxidants, were heated for 12 h/d at approximately 190°C in a small deep-fat fryer until the polymer concentration exceeded 20%, as determined by high-performance size-exclusion chromatography. Increases in the free fatty acid content, total acid value, food oil sensor value, and p-anisidine value during heating indicated that significant thermal oxidation had occurred in each oil. Capillary supercritical fluid chromatography (SFC) was used to determine the substrate concentration of each oil after each heating interval. The average, apparent firstorder reaction rate constant (as determined by SFC) for trilinolein was 0.0348 ± 0.0034 h −1 , while the rate for EPG-08 linoleate was 0.0253 ± 0.0032 h −1 . The average apparent reaction rate constant for triolein was 0.0256 ± 0.0011 h −1 , while the rate for EPG-08 oleate was 0.0252 ± 0.0008 h −1 . Triolein contained >20% polymer after 60 h of heating, EPG-08 oleate contained >20% polymer after 36 h of heating, and both trilinolein and EPG-08 linoleate contained >20% polymer after 24 h of heating. JAOCS 74, 367-374 (1997). FIG. 1. High-performance size-exclusion chromatography of heated (190°C, 12 h/d) EPG-08 linoleate (ARCO Chemical Co., Newtown Square, PA).