Abstract:Ferroelectric memories (FeRAMs) are more and more using stack cells in 1T1C configuration. While none of these are already in real production, a great progress has been made when comparing these with strapped cells in 2T2C configuration. However the FeRAM community must be ready to face another challenging step in the evolution, i.e. the transition from planar to 3D capacitors. There's no consensus on the best approach to address this issue, which is probably a must at the 130 nm node. This paper reviews the l… Show more
“…The use of CNTs as templates or as bottom electrodes is a potential strategy to realize 3D ferroelectric nanostructures. − However, in the last few years only a few reports on the investigation of multiwalled carbon nanotubes (MWCNTs) covered with ferroelectrics for 3D capacitors and related applications have been published. ,,− The use of MWCNTs for this application is limited by the requirement to process ferroelectrics at high temperatures (>600 °C) in oxidizing atmospheres, which results in an exothermic reaction. From our previous studies on the thermal stability of MWCNTs in different atmospheres, we have demonstrated that MWCNTs are stable up to 420 °C in air but in higher P(O 2 ) they oxidize at ≥200 °C.…”
Carbon nanotubes (CNTs) have the potential to act as templates or bottom electrodes for three-dimensional (3D) capacitor arrays, which utilize one-dimensional (1D) ferroelectric nanostructures to increase the memory size and density. However, growing a ferroelectric on the surface of CNTs is nontrivial. Here, we demonstrate that multiwalled (MW) CNTs decrease the time and temperature for the formation of lead zirconium titanate Pb(Zr1-xTix)O3 (PZT) by ∼100 °C commensurate with a decrease in activation energy from 68 ± 15 to 27 ± 2 kJ/mol. As a consequence, monophasic PZT was obtained at 575 °C for MWCNTs/PZT, but for pure PZT, traces of pyrochlore were still present at 650 °C, where the PZT phase formed due to homogeneous nucleation. The piezoelectric nature of MWCNTs/PZT synthesized at 500 °C for 1 h was proven. Although further work is required to prove the concept of 3D capacitor arrays, our result suggests that it is feasible to utilize MWCNTs as templates/electrodes for the formation of 1D PZT nanoferroelectrics.
“…The use of CNTs as templates or as bottom electrodes is a potential strategy to realize 3D ferroelectric nanostructures. − However, in the last few years only a few reports on the investigation of multiwalled carbon nanotubes (MWCNTs) covered with ferroelectrics for 3D capacitors and related applications have been published. ,,− The use of MWCNTs for this application is limited by the requirement to process ferroelectrics at high temperatures (>600 °C) in oxidizing atmospheres, which results in an exothermic reaction. From our previous studies on the thermal stability of MWCNTs in different atmospheres, we have demonstrated that MWCNTs are stable up to 420 °C in air but in higher P(O 2 ) they oxidize at ≥200 °C.…”
Carbon nanotubes (CNTs) have the potential to act as templates or bottom electrodes for three-dimensional (3D) capacitor arrays, which utilize one-dimensional (1D) ferroelectric nanostructures to increase the memory size and density. However, growing a ferroelectric on the surface of CNTs is nontrivial. Here, we demonstrate that multiwalled (MW) CNTs decrease the time and temperature for the formation of lead zirconium titanate Pb(Zr1-xTix)O3 (PZT) by ∼100 °C commensurate with a decrease in activation energy from 68 ± 15 to 27 ± 2 kJ/mol. As a consequence, monophasic PZT was obtained at 575 °C for MWCNTs/PZT, but for pure PZT, traces of pyrochlore were still present at 650 °C, where the PZT phase formed due to homogeneous nucleation. The piezoelectric nature of MWCNTs/PZT synthesized at 500 °C for 1 h was proven. Although further work is required to prove the concept of 3D capacitor arrays, our result suggests that it is feasible to utilize MWCNTs as templates/electrodes for the formation of 1D PZT nanoferroelectrics.
“…One concern towards scaling is its charge-based operation and limited polarization signal, requiring the development of 3-dimensional (3-D) structures [1].…”
“…the ferroelectric capacitor, 'FeCAP') are required to attain a larger polarization signal per unit area of the memory cell. Thus, in the replacement of conventional planar capacitors, recent developments have been oriented toward integration of three-dimensional capacitors (Goux, Russo et al, 2005;Scott, 2005a,b;Scott et al, 2005;Nagel et al, 2004;Joshi, 2004;Narayan, 2003;Zambrano, 2003;Johnson et al, 2003). Lead zirconate titanate (PbZr 1Àx Ti x O 3 , PZT) is the most used ferroelectric material for planar capacitors and is also used for three-dimensional capacitor scaling (Nagai et al, 2006(Nagai et al, , 2005; Koo et al, 2005;Kim et al, 2005;Funakubo et al, 2005).…”
Section: Introductionmentioning
confidence: 99%
“…Nevertheless, much attention is also focused on the integration of strontium bismuth tantalate (SrBi 2 Ta 2 O 9 , SBT) in threedimensional capacitors or in nanotubes (Morrison et al, 2003). Indeed, this material fulfills the requirements for highly reliable devices: high resistance to fatigue, long polarization retention, low leakage, negligible imprint and no degradation of electrical properties for ultra-thin films (Zambrano, 2003;Celinska et al, 2003;Scott, 2000;Paz de Araujo et al, 1995). Besides their good intrinsic electrical properties, high-quality polycrystalline SBT thin films are successfully elaborated by metal organic chemical vapour deposition (MOCVD) and fully integrated within a microelectronic architecture (Goux, Russo et al, 2005;Johnson et al, 2003;Narayan, 2003).…”
Future development of ferroelectric random access memory requires the integration of three-dimensional ferroelectric capacitors (FeCAP) in a microelectronic architecture. In this paper, pin-shaped two-dimensional and three-dimensional Sr 0.8 Bi 2.2 Ta 2 O 9 -based FeCAP arrays were characterized using an original approach combining micro-focused synchrotron X-ray fluorescence and diffraction. From a modelling approach, dimensional, chemical and microstructural details were extracted over a series of capacitor arrays. Hence, these techniques proved insightful for a non-destructive benchmarking approach. In addition, for all investigated capacitor geometries, the microfluorescence experiments evidenced a well controlled chemical composition within the FeCAP arrays, attesting the stability of the elaboration and integration steps. Nevertheless, micro-diffraction experiments have indicated a lower control of the ferroelectric film crystallographic orientation from one capacitor to the next, despite a well defined chemical composition. This feature was attributed to the presence of patterned bottom electrodes, bringing to light the role of the slanted capacitor sidewalls in the three-dimensional geometry and partially explaining the non-optimized electrical polarization usually measured in three-dimensional capacitors with respect to planar geometry. research papers J. Appl. Cryst. (2006). 39, 376-384 N. Menou et al. Integrated pin-shaped ferroelectric capacitors 377
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