Abstract:Ceria‐modified mineral‐like copper catalyst 12 %Cu/SiO2−CeO2 showed a high activity and selectivity in one‐pot hydroamination of bio‐available 5‐hydroxymethylfurfural with nitro‐aromatic compounds. The catalyst was obtained by conventional deposition‐precipitation method with urea from commercial silica, copper nitrate, and ammonium cerium (IV) nitrate. The synthesized catalyst with a copper phyllosilicate structure formed inside the pores of silica was studied by XRD, N2 adsorption, XPS, SEM and TEM methods. … Show more
Precursors of ammonium salt biosurfactants have been obtained from HMF by coupling cobalt-catalyzed reductive amination with selective bio-esterification using an immobilized lipase CALB. The process has been optimized in batch and flow reactors.
Precursors of ammonium salt biosurfactants have been obtained from HMF by coupling cobalt-catalyzed reductive amination with selective bio-esterification using an immobilized lipase CALB. The process has been optimized in batch and flow reactors.
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