Chemoenzymatic synthesis of amino-esters as precursors of ammonium salt-based surfactants from 5-hydroxymethylfurfural (HMF)
Carlos Moriana Herraiz,
Karen S. Arias,
Maria J. Climent
et al.
Abstract:Precursors of ammonium salt biosurfactants have been obtained from HMF by coupling cobalt-catalyzed reductive amination with selective bio-esterification using an immobilized lipase CALB. The process has been optimized in batch and flow reactors.
A transfer hydrogenative reductive amination of 5-(hydroxymethy)furfural (HMF) has been accomplished catalyzed by a cyclometalated iridium catalyst with formic acid as a hydrogen source. The catalytic system afforded a TON...
A transfer hydrogenative reductive amination of 5-(hydroxymethy)furfural (HMF) has been accomplished catalyzed by a cyclometalated iridium catalyst with formic acid as a hydrogen source. The catalytic system afforded a TON...
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