A Pt/CeO2‐ZrO2 catalytic system was able to initiate an extremely intense hydrogen spillover providing a huge amount of activated hydrogen (12 mol/mol Pt) at temperatures –50°C ‐ +25°C, which was not observed before. The idea was to use this activated hydrogen for reduction of carbonyl compounds under ambient conditions. Thus, the efficient and selective heterogeneous hydrogenation of carbonyl compounds of different structure, including 5‐hydroxymethylfurfural and cinnamaldehyde, to the corresponding alcohols with quantitative yields was successfully performed over the Pt/CeO2‐ZrO2 catalysts at room‐temperature and atmospheric pressure of H2. The proposed catalysts afforded hydrogenation under significantly milder conditions with a much higher activity and selectivity compared to the commercial catalysts and reported catalytic systems. Hydrogenation of the C=O bond in the presence of a C=C bond proceeded with a high regioselectivity.
The
use of available renewable sources of raw materials for the
production of various organic compounds has long been undoubted and
recognized throughout the world. However, the development of efficient
“green” catalytic technologies for the processing of
bioavailable compounds, namely, the synthesis of catalysts and the
selection of optimal process conditions, has become a real challenge
for researchers nowadays. In this work, 2,5-bis(hydroxymethyl)furan,
an intermediate for the production of a number of biobased polymer
materials, was obtained by hydrogenation of 5-hydroxymethylfurfural
in a yield close to quantitative at room temperature and atmospheric
pressure in the presence of a catalytic system with 1% wt of platinum
as an active phase supported on ceria–zirconia mixed oxide.
On the low-loaded 0.25% Pt/CeO2–ZrO2 catalyst,
the yield of the desired alcohol as high as 87% has been achieved
after a slight increase of H2 pressure from 0.1 to 0.5
MPa.
A new reality of the 21st century is the transition to a new type of economy and energy concepts characterized by the replacement of existing petrochemical routes to a bio-based circular economy. The needs for new strategies in obtaining basic products from bio-based resources with minimum CO2 traces has become mandatory. In this review, recent trends in the conversion of biomass-derived molecules, such as simple monomeric sugars and cellulose, to industrially important C5 and C6 sugar alcohols on heterogeneous catalysts based on non-noble metals are discussed focusing on the influence of catalyst structures and reaction conditions used on the substrate conversion and product selectivity. The challenges and prominent ideas are suggested for the further development of catalytic hydrogenation of naturally abundant carbohydrates to value-added chemicals on non-noble metal catalysts.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.