We report a new analysis of electron mobility in HfO 2 / TiN gate metal-oxide-semiconductor field effect transistors ͑MOSFETs͒ by investigating the influence of HfO 2 thickness ͑1.6-3 nm͒, temperature ͑50-350 K͒, and oxide charge ͑ϳ1 ϫ 10 11 -8ϫ 10 12 cm −2 ͒ in the high inversion charge region. The fixed oxide charge and interface state densities are deliberately increased using negative-bias-temperature stress, allowing the determination of the Coulomb scattering term as a function of temperature for various oxide charge levels. The temperature dependence of the Coulomb scattering term is consistent with the case of a strongly screened Coulomb potential. Using the experimentally determined temperature dependence of Coulomb scattering term, a model is developed for the electron mobility, including the effects oxide charge ͑ C ͒, high-k phonon ͑ Ph-Hk ͒, silicon phonon ͑ Ph-Si ͒, and surface roughness scattering ͑ SR ͒. The model provides an accurate description of the experimental data for variations in HfO 2 thickness, temperature, and oxide charge. Using the model the relative contributions of each mobility component are presented for varying oxide charge and high-k thickness. Scaling of the HfO 2 physical thickness provided a reduction in the oxide charge and high-k phonon scattering mechanisms, leading to an increase in electron mobility in HfO 2 / TiN gate MOSFETs.