Binder and carbon-free SbSn-P nanocomposite thin films as anode materials for sodium-ion batteries

One‐Step In Situ Synthesis of Three‐Dimensional NiSb Thin Films as Anode Electrode Material for the Advanced Sodium‐Ion Battery

“…This is consistent with the discharge profile plateaux at 0.5 and 0.3 V . The almost overlapping cycles reveal the excellent cycle stability of the NiSb anode during the sodiation/desodiation process.…”

Electrodeposited Binder‐Free Antimony−Iron−Phosphorous Composites as Advanced Anodes for Sodium‐Ion Batteries

“…For instance, Zhou et al fabricated SnÀ Sb/P nanocomposites that exhibited better cycling performance than SnÀ Sb, Sb, or Sn thin films. [28] MP-based composites such as SbÀ CoÀ P and FeÀ SnÀ SbÀ P, [29,30] which contain one inactive element and two or three active elements with different working voltages, have been used as anode materials for LIBs and achieved a good lifespan with high specific capacities because of synergistic contributions of the composition and microstructure. Moreover, Sb is considered a prospective anode material for SIBs owing to its high theoretical capacity of 660 mA h g À 1 (Sb + 3 Na + + 3 e À ⇋Na 3 Sb) and a moderate working voltage (~0.6 V) with a flat potential plateau.…”

“…For instance, Zhou et al . fabricated Sn−Sb/P nanocomposites that exhibited better cycling performance than Sn−Sb, Sb, or Sn thin films . MP‐based composites such as Sb−Co−P and Fe−Sn−Sb−P, which contain one inactive element and two or three active elements with different working voltages, have been used as anode materials for LIBs and achieved a good lifespan with high specific capacities because of synergistic contributions of the composition and microstructure.…”

Pulsed Laser Deposition‐based Thin Film Microbatteries

“…[121] Similar mechanisms in addition to LiÀ Zn alloying were proposed for ZnFe 2 O 4 and Agdoped ZnFe 2 O 4 . [122] Other examples of anodes include LiNiVO 4 [123] with 7 Li ions per LiNiVO 4 , alloying and selenidation were found in Ag 2 Se with 5.6 Li ions per Ag 2 Se transferred, [124] FeSe, [125] Sb 2 Se 3 [126] and SnSe, [127] composites of Sb 2 Se 3 and Li 2 Se, [128] SnO 2 À Se and ZnOÀ Se composites that show redox of the SnO 2 /ZnO component and selenidation/reduction of SnSe, [129] SnSÀ SnSe composites, [130] Sn, [131] the copper selenide family, [132] InSe, [133] CuInSe 2 , [134] composites of amorphous SnO x and nanoscrystalline SnO 2 , [135] CeO 2 , [136] amorphous [137] and crystalline [138] Si, Si/TiN composite, [137b] SiO 1.3 examined in an ionic liquid electrolyte, [139] ZnO 1À x S x with x = 0.72 showing the best electrochemical performance, [140] Mg 2 Si, [141] NiCo 2 S 4 , [142] Li 2 Si 3 S and FeS composite, [143] TiS x where amorphous TiS 4 was examined in an all solid state cell, [144] Cu 2 Sb, [145] SbSnÀ P composite, [146] CoSn 2 and CrSn 2 , [147] LiF/Ti, [148] LiF/Co and LiF/Ni nanocomposite films where there was evidence of the decomposition of LiF during cycling, [149] Sn 4 P 3 , [150] CrP, [151] InP, [152] CoP which forms Co/Li 3 P on discharge, [153] Li 3 PÀ VP composite, [154] AlNÀ Fe and AlNÀ Co composites, [155] NiSi, [156]…”

“…Other examples of anodes include LiNiVO 4 with 7 Li ions per LiNiVO 4 , alloying and selenidation were found in Ag 2 Se with 5.6 Li ions per Ag 2 Se transferred, FeSe, Sb 2 Se 3 and SnSe, composites of Sb 2 Se 3 and Li 2 Se, SnO 2 −Se and ZnO−Se composites that show redox of the SnO 2 /ZnO component and selenidation/reduction of SnSe, SnS−SnSe composites, Sn, the copper selenide family, InSe, CuInSe 2 , composites of amorphous SnO x and nanoscrystalline SnO 2 , CeO 2 , amorphous and crystalline Si, Si/TiN composite, SiO 1.3 examined in an ionic liquid electrolyte, ZnO 1−x S x with x=0.72 showing the best electrochemical performance, Mg 2 Si, NiCo 2 S 4 , Li 2 Si 3 S and FeS composite, TiS x where amorphous TiS 4 was examined in an all solid state cell, Cu 2 Sb, SbSn−P composite, CoSn 2 and CrSn 2 , LiF/Ti, LiF/Co and LiF/Ni nanocomposite films where there was evidence of the decomposition of LiF during cycling, Sn 4 P 3 , CrP, InP, CoP which forms Co/Li 3 P on discharge, Li 3 P−VP composite, AlN−Fe and AlN−Co composites, NiSi, NiO−NiSe, NiSe 2 , ZnSe, so‐called GaN@Cu, Li 3 N−Co composite which produces Li 2.57 Co 0.43 N on discharge, Li 3 N−Si, SiN 0.92 , Cr 2 O 3 , Cr 2 O 3 −InP, Co−Li 2 S composites, Co 3 O 4 , ZnO, FeOF, Fe 2 O 3 , Fe 2 O 3 −Se, MoO 2 , GeO 2 , In 2 O 3 , Sb 2 O 3 , CoO−Co composite,…”