2016
DOI: 10.1016/j.mssp.2015.12.018
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Antimony sulfide (Sb2S3) thin films by pulse electrodeposition: Effect of thermal treatment on structural, optical and electrical properties

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Cited by 92 publications
(13 citation statements)
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“…The XPS spectrum of Sb 2 S 3 /TiO 2 exhibited two peaks in the S 2p region at 161.4 and 162.4 eV correspond to S 2p 1/2 and S 2p 3/2 of divalent S in Figure 3c [16,19,41]. The peaks at 529.3 and 538.7 eV in the Sb 3d region for Sb 2 S 3 /TiO 2 , respectively, are assigned the Sb 3+ oxidation state of Sb and are consistent with the earlier-reported values of Sb 2 S 3 [19,[42][43][44]. The relatively weak peak at 531.…”
Section: Characterization Structure Of Different Samplessupporting
confidence: 89%
“…The XPS spectrum of Sb 2 S 3 /TiO 2 exhibited two peaks in the S 2p region at 161.4 and 162.4 eV correspond to S 2p 1/2 and S 2p 3/2 of divalent S in Figure 3c [16,19,41]. The peaks at 529.3 and 538.7 eV in the Sb 3d region for Sb 2 S 3 /TiO 2 , respectively, are assigned the Sb 3+ oxidation state of Sb and are consistent with the earlier-reported values of Sb 2 S 3 [19,[42][43][44]. The relatively weak peak at 531.…”
Section: Characterization Structure Of Different Samplessupporting
confidence: 89%
“…As show in Figure a, in the range between 150 and 600 cm −1 , both of the Raman spectra exhibited similar behaviors, and four peaks at 188, 237, 280, and 303 cm −1 could be observed. The peaks centered at 188, 237, 280, and 303 cm −1 could correspond to the vibration of the SbSb bond for Sb 2 S 3 structural units, to the antisymmetric SSbS vibration, the antisymmetric vibrations of SbS stretching in pyramidal symmetry, and the symmetric stretching of the SbS structural units, respectively . On the contrary, the Raman spectra in the range of 1300–1700 cm −1 displayed very different behaviors (Figure b).…”
Section: Resultsmentioning
confidence: 95%
“…The Sb 3d 5/2 spectrum was superimposed by the O 1s signal at a binding energy of E bin ≈ 532.5 eV. The asymmetry of the Sb 3d 5/2 component to low E bin indicated two oxidation states, 529.5 eV for Sb 3+ and 530.4 eV for Sb 5+ , confirming the Sb–S chemical environment in the surface region. The O 1s peak was asymmetric to high E bin , suggesting the presence of at least two chemical states, at 532.0 and 532.9 eV (Figure a). These states can probably be attributed to oxygenated Si, Sb, P, and/or Ge.…”
mentioning
confidence: 92%