Anisotropic compressive properties of porous CNT/SiC composites produced by direct matrix infiltration of CNT aerogel

Abstract

Carbon nanotube‐reinforced silicon carbide composites (CNT/SiC) produced by direct infiltration of matrix into a porous CNT arrays have been demonstrated to possess a unique microstructure and excellent micro‐mechanical properties. However, the thickness of the array preforms is usually very small, typically less than 2 mm. Therefore, fabrication of macroscopic CNT/SiC composites by chemical vapor infiltration (CVI) process requires that the nanoscale fillers could form macroscopic architectures with an open pore network. Here, this study reports an experimental strategy for the fabrication of SiC matrix composites reinforced by CNT based on an ice‐segregation‐induced self‐assembly (ISISA) technique. Macroscopic CNT aerogel with well‐defined macroporous network was produced by ISISA technique and was subsequently infiltrated by SiC in a CVI reactor. After five CVI cycles, the porosity of as‐fabricated composites was 11.6±0.3% and the machined specimens exhibited lamellar structure with parallel lamellaes intersected at discrete angles. By observed, there are in fact five different representative anisotropic macrostructures, the compressive strengths of these five different loading modes with respect to lamella orientation were 933±55, 619±34, 200±45, 199±21, and 297±41 MPa, respectively, and the failure mechanisms were attributed to the anisotropic nature of the macrostructures. Energy dissipation toughening mechanism at the nanoscale such as CNT pull‐out was observed and the phase composition of the fabricated materials included β‐SiC, CNT, and SiO2.

Freeze casting – A review of processing, microstructure and properties via the open data repository, FreezeCasting.net

“…For anisotropic pore structures, compressive strength is typically reported for loads applied parallel to the wall direction. In the cases where compressive strength is reported for loading perpendicular to the wall direction (in addition to parallel loading), anisotropic compressive strength properties, where increased strengths for parallel loading, are reported [186,308,[461][462][463][464][465]. Increased flexural [186] strength, and elastic moduli [193] are also reported for parallel loading in comparison to perpendicular loading.…”