Anionic Nanochanneled Silver-Deficient Oxalatochromate(III) Complex with Hydroxonium as Counter Ion: Synthesis, Characterization and Crystal Structure

Eboga, Clémence T.; Bebga, Gouet; Mbiangué, Yves A.; Nfor, Emmanuel N.; Djonwouo, Patrick L.; Bélombé, Michel M.; Nenwa, Justin

doi:10.4236/ojic.2017.73005

Cited by 7 publications

(3 citation statements)

References 24 publications

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“…One could consider with serenity the fabrication of a compound in which the organic cation compensating the charge of the anionic complex would be solely replaced by small charged species such as hydronium ions. Such a system with protons balancing the negative charge of the anionic framework could be a good candidate for the exploration of the concept of one-dimensional proton conducting solids [33] [34] [35]. It could be also worth studying the magnetic properties of 1 as well as its antibacterial activities as with related compounds [10] [13].…”

Section: Discussionmentioning

confidence: 99%

Synthesis, Characterization and Thermal Analysis of an Organic-Inorganic Hybrid Salt Involving Trans-Diaquabis(oxalato-κ2O1,O2)chromate(III) Complex Anion with Piperidinium as Counter Cation

Ndong¹,

Signé²,

Kenfack³

et al. 2020

CSTA

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A new organic-inorganic hybrid salt pipéridinium trans-diaquabis(oxalato)chromate(III) tetrahydrate, (C 5 H 10 NH 2 )[Cr(C 2 O 4 ) 2 (H 2 O) 2 ]•4H 2 O (1), has been synthesized in water and characterized by FTIR and UV-Vis spectroscopies, elemental and thermal analyses and by single-crystal X-ray diffraction. 1 crystallizes in the orthorhombic non-centrosymmetric space group Cmc2 1 with the unit cell parameters a = 7.4329(3), b = 9.9356(5), c = 23.6756(11) Å, α = β = γ = 90˚, V = 1748.45(14) Å 3 and Z = 4. The structure of 1 consists of [Cr(C 2 O 4 ) 2 (H 2 O) 2 ] − mononuclear anions, piperidinium cations and uncoordinated water molecules. The Cr III ion in the complex [Cr(C 2 O 4 ) 2 (H 2 O) 2 ] − is coordinated in a slightly distorted octahedral environment by four O atoms from two chelating oxalate dianions in the equatorial plane, and two O atoms from trans-coordinated water molecules occupying the apical positions. In the crystal, N-H⋯O and O-H⋯O hydrogen bond interactions connect the components into a 3-D framework. The IR spectrum of 1 is consistent with the presence of the various molecular building constituents, namely oxalato and aqua ligands, piperidinium cations and solvent water molecules. The UV-Vis spectrum shows two absorption bands around 564 and 416 nm which are

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Section: Discussionmentioning

confidence: 99%

Synthesis, Characterization and Thermal Analysis of an Organic-Inorganic Hybrid Salt Involving Trans-Diaquabis(oxalato-κ2O1,O2)chromate(III) Complex Anion with Piperidinium as Counter Cation

Ndong¹,

Signé²,

Kenfack³

et al. 2020

CSTA

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“…In our research group, the replacement of organic cations in these hybrid salts by small positive charged species such as hydronium (H 3 O + ) cations, compensating the negative charge of the anionic complex is under way. Such systems, no doubt, could be well-adapted models to monitor the exploration of the concept of protonic charge transport processes in the solid state [35] [36] [37].…”

Section: Discussionmentioning

confidence: 99%

A Novel Chromium(III) Hybrid Salt, Triethylammonium Trans-Diaquabis(Oxalato-κ2O1,O2) Chromate(III), (C6H16N)[Cr(C2O4)2(H<S

Signé¹,

Ndong²,

Kenfack³

et al. 2020

OJIC

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A novel organic-inorganic chromium(III) hybrid salt, triethylammonium trans-diaquabis(oxalato-κ 2 O 1 ,O 2)chromate(III), (C 6 H 16 N)[Cr(C 2 O 4) 2 (H 2 O) 2 ] (1), has been synthesized in aqueous solution and characterized by elemental and thermal analyses, FTIR and UV-Vis spectroscopies, and by single crystal X-ray structure determination. Compound 1 crystallizes in the orthorhombic system, Pbcn space group with the unit cell parameters a = 11.1776(10), b = 7.6105(10), c = 17.5654(2) Å, α = β = γ = 90˚, V = 1494.24(3) Å 3 , Z = 4 and Z' = 1/2. The structure of 1 consists of [Cr(C 2 O 4) 2 (H 2 O) 2 ] − mononuclear anions and triethylammonium [(C 2 H 5) 3 NH] + cations. In the anionic unit, the Cr III ion is six coordinated, in a distorted octahedral geometry, by four equatorial O atoms of two oxalate anions acting as chelating ligands and two O atoms from trans-coordinated water molecules occupying the apical positions with longer metal-oxygen distances. In the solid, O-H … O and N-H … O intra and inter molecular hydrogen bonding interactions connect the components into a 3D network. The triethylammonium cations are disordered among two possible orientations with occupancies rates around 50% for C4, N1, C1a, C1b, C4 ii , N1 ii , C1a ii , C1b ii

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“…These salts might further be used as precursors for the development of novel systems in which organic cations are replaced by small inorganic charged species such as hydronium (H3O + ) cations. Materials of this type, no doubt, could be well-adapted models in the exploration of the concept of onedimensional proton conducting solids [15,16]. As a first example of hybrid salts with a great amount of pyridinium derivatives as counter cations, we report here the synthesis, crystal structure and magnetic properties of two new heterometallic heptanuclear oxalato-bridged [Ba II 3M III 4] complexes, (C5H7N2)6[Ba3(H2O)5.1Cr4(C2O4)12]•5H2O (1) and (C5H7N2)6[Ba3(H2O)5.3Fe4(C2O4)12]•5H2O (2) (C5H7N2 + : 3-aminopyridinium cation).…”

Section: Introductionmentioning

confidence: 99%

Two isostructural oxalato-bridged dimetallic heptanuclear [BaII3MIII4] complexes (M = Cr; Fe) associated with 3-aminopyridinium cations: Synthesis, crystal structure and magnetic properties

et al. 2021

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Anionic Nanochanneled Silver-Deficient Oxalatochromate(III) Complex with Hydroxonium as Counter Ion: Synthesis, Characterization and Crystal Structure

Cited by 7 publications

References 24 publications

Synthesis, Characterization and Thermal Analysis of an Organic-Inorganic Hybrid Salt Involving <i>Trans</i>-Diaquabis(oxalato-κ<sup>2</sup><i>O</i><sup>1</sup>,<i>O</i><sup>2</sup>)chromate(III) Complex Anion with Piperidinium as Counter Cation

Synthesis, Characterization and Thermal Analysis of an Organic-Inorganic Hybrid Salt Involving <i>Trans</i>-Diaquabis(oxalato-κ<sup>2</sup><i>O</i><sup>1</sup>,<i>O</i><sup>2</sup>)chromate(III) Complex Anion with Piperidinium as Counter Cation

A Novel Chromium(III) Hybrid Salt, Triethylammonium <i>Trans</i>-Diaquabis(Oxalato-<i>κ</i><sup>2</sup>O<sup>1</sup>,O<sup>2</sup>) Chromate(III), (C<SUB>6</SUB>H<SUB>16</SUB>N)[Cr(C<SUB>2</SUB>O<SUB>4</SUB>)<SUB>2</SUB>(H<S

Two isostructural oxalato-bridged dimetallic heptanuclear [BaII3MIII4] complexes (M = Cr; Fe) associated with 3-aminopyridinium cations: Synthesis, crystal structure and magnetic properties

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