We measured the resonant nonlinear optical absorption and refraction due to intersubband transitions in GaN/AlGaN multiple quantum well structures at 1.5 mm. The measured values are much smaller than that predicted by theoretical studies. This is attributed to a larger than expected dephasing of excited electrons. At high excitation intensity, the absorption can be saturated.The resonant optical response from intersubband transitions (ISBT) in GaN/AlGaN quantum well (QW) structures is found to be well below a picosecond [1,2]. In addition, the resonant frequencies of these structures can now be tuned to overlap the telecommunication window centered around 1.55 mm [3]. It is thus conceivable to utilize the nonlinear optical response of these structures for practical ultrafast devices in all-optical communication and logic networks [4]. In this paper, we discuss measurements that quantify their nonlinear susceptibility (c ð3Þ ) in the weak field regime and the absorption saturation intensity under high excitation intensity. We show that the optical nonlinearity of these structures is smaller than previously predicted [5], leading to higher than expected saturation intensity. We attribute this small nonlinearity to the fast dephasing of the excited carriers.The structures were MBE grown on c-axis sapphire substrate [6]. Two types of samples were studied. The single QW samples consist of 15 or 100 sets of 12 â GaN QW bounded by 3 periods of Al 0:65 Ga 0:35 N/GaN (15 â/7.8 â) superlattice barriers, whereas the coupled QW structure consists of 25 sets of GaN/Al 0:85 Ga 0:15 N/GaN (12 â/10 â/12 â) bounded by 50 â layers of Al 0:85 Ga 0:15 N barriers [7]. They are both Si-doped in the QWs with a doping concentration of 10 19 À10 20 cm À3 . Linear absorption measurements were performed in the multi-pass geometry, shown in the inset of Fig. 1. In this configuration, the edges of the sample were polished at 45 to the surface to form a planar waveguide. For a half centimeter sized sample, the incident beam typically bounces back and forth roughly ten times. The transmission spectra shown in Fig. 1 were taken from the 15-well single QW sample using s-or p-polarized light. The ISBT transitions in the QWs can only be induced by fields that are perpendicular to the QW plane. Therefore, the absorption only occurs for the p-polarized light in the ideal case. Fig. 1b shows the absorption of p-polarized input light normalized to that of the s-polarized light. Details for the linear absorption of the coupled QW structures can be found in Ref. [7].The pump and probe experiments were performed in the single-pass configuration, shown in the inset of Fig. 2a. The two incident beams form a $15angle and the probe beam forms a $45 angle