Eucalyptus wood is one of the important
hardwood resources with
attractive properties of rapid growth and good quality, which are
widely used for the manufacture of wood-based boards, furniture, pulp
and paper, and so on. In order to explore the potential of sawdust
waste from the eucalyptus wood furniture factory as a bioenergy feedstock,
its pyrolysis properties after different solvent extractions were
examined using thermogravimetric analysis coupled with Fourier transform
infrared spectrometry. The mass ratio of extractives in eucalyptus
wood sawdust by benzene–alcohol, hot water, and sodium hydroxide
solution was 4.25, 9.68, and 16.11%, respectively. After extraction,
the thermal decomposition process of eucalyptus wood was promoted
with a higher weight loss rate, lower activation energy, and lower
residue content compared to the raw sample without pretreatment, and
the promotion level was positively correlated to the strength of extracting
solvent. CO
2
, CO, CH
4
, H
2
O, acids,
aldehydes, aromatics, ethers, and alcohols were identified as the
important intermediates in pyrolysis vapors, which can be tuned by
different extraction pretreatments. In terms of typical gas products,
benzene–alcohol enhanced the release of carbon dioxide, and
hot water enhanced the water generation from dehydration reactions
and slightly increased the production of carbon monoxide, while sodium
hydroxide promoted the formation of methane at the early stage under
280 °C and later stage over 460 °C during the pyrolysis
of eucalyptus wood. It is believed that the extraction pretreatment
can not only obtain the bioactive extractive products but also benefit
the pyrolysis process by lowering the energy barrier and tuning the
composition of pyrolysis products.