Accommodation of nonplanarity is required in a monolithic waferlevel three-dimensional (3D) technology platform, in which two damascene patterned copper/benzocyclybutene (BCB) layers are bonded to form mechanical bonds between wafers and inter-wafer copper interconnects. The temperature dependence of the surface energy of partially-cured BCB, an important material parameter for determining accommodation of nonplanarities, is characterized using contact angle measurements and varies in the range of 39-50 mJ/m 2 between 35 o C and 230 o C. These changes are discussed with respect to the surface structure and mechanical properties of the BCB, and should not be a barrier to usage of partially-cured BCB as a bonding material.