A study of pyrolysis and pyrolysis products of flame-retardant cotton fabrics by DSC, TGA, and PY–GC–MS

Peng, Zhu; Sui, Shuying; Wang, Bing; Sun, Kai; Sun, Gang

doi:10.1016/j.jaap.2003.09.005

Cited by 234 publications

(120 citation statements)

References 7 publications

(18 reference statements)

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“…For example, pyrolysis process of flame retardant treated and untreated cotton fabrics were investigated. It was reported that, addition of flame retardant catalyzed the dewatering and carbonizing reaction of the cellulose [68]. This catalyzing effect reduced the production of flammable products, inducing a better fire retardation.…”

Section: Pyrolysis-gas Chromatography (Py-gc)mentioning

confidence: 99%

An Overview of Mode of Action and Analytical Methods for Evaluation of Gas Phase Activities of Flame Retardants

et al. 2015

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Abstract:The latest techniques used to prove, describe and analyze the gas phase activity of a fire retardant used in polymeric materials are briefly reviewed. Classical techniques, such as thermogravimetric analysis or microscale combustion calorimetry, as well as complex and advanced analytical techniques, such as modified microscale combustion calorimeter (MCC), molecular beam mass spectroscopy and vacuum ultra violet (VUV) photoionization spectroscopy coupled with time of flight MS (TOF-MS), are described in this review. The recent advances in analytical techniques help not only in determining the gas phase activity of the flame-retardants but also identify possible reactive species responsible for gas phase flame inhibition. The complete understanding of the decomposition pathways and the flame retardant activity of a flame retardant system is essential for the development of new eco-friendly-tailored flame retardant molecules with high flame retardant efficiency.

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Section: Pyrolysis-gas Chromatography (Py-gc)mentioning

confidence: 99%

An Overview of Mode of Action and Analytical Methods for Evaluation of Gas Phase Activities of Flame Retardants

et al. 2015

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“…Different equipment can be used to measure the pyrolysis products of biomass. Many researchers have used pyrolysis gas chromatography-mass spectroscopy to study the pyrolysis of cotton [5], pine wood [6], paper [7] and others [8], [9]. Moreover, thermogravimetry coupled with Fourier Transform Infrared Spectroscopy were used successfully to determine products of pyrolysis [10], [11].…”

Section: Introductionmentioning

confidence: 99%

Pyrolysis Characteristics of Phoenix Dactylifera Date Palm Seeds Using Thermo-Gravimetric Analysis (TGA)

Babiker¹,

Aziz²,

Heikal³

et al. 2013

IJESD

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Abstract-Mass losses of Phoenix dactylifera date palm seeds (DPSs) were measured using a thermo-gravimetric analyzer (TGA). Six-milligram-sample of six varieties of DPSs were pyrolyzed in an inert condition (argon atmosphere) with a constant flow rate of 100 ml/min for the entire range of experiments. The experiments were conducted under non-isothermal conditions and at a heating rate of 20°C/min until the furnace wall temperature reached 900°C. The moisture (M), ash (ASH), volatile matter (VM) and fixed carbon (FC) of the selected date seeds were determined by means of proximate analysis. The weight percentages of carbon (C), hydrogen (H), oxygen (O), nitrogen (N), sulfur (S) and atomic ratios (H/C and O/C) were determined through the ultimate analysis. The heating value, bulk and particle density of DPSs were also measured using a bomb calorimeter and ultra-pycnometer, respectively. The yield of the liquids was obtained by subtracting the total gaseous mass from the DTG data. The experiments demonstrated that there were significant differences in physiochemical properties of selected DPSs. The findings also revealed that DPSs contain much volatile compounds. DPSs energy densities were found to be among the high-quality biological feedstocks.Index Terms-Date palm seeds, pyrolysis, TGA, thermal characteristic.

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“…A crosslinker trimethylol melamine (TMM) is generally used for enhancing adhesive force of cellulosic material (Uddin 2013), this increase the nitrogen content for the synergistic effect of the FR-treatment with the phosphorus group of the MDPA (Yasin et al 2016b). The cellulosic materials treated with FR having phosphorus and nitrogen elements, goes through catalyzed reactions of dewatering, decarboxylation and charring, which may produce other fragmented products (Zhu et al 2004). Consequently, the influence of FR elements such as phosphorus and nitrogen in the cellulosic material can drop the gasification temperature drastically and increase or decrease the byproducts.…”

Section: Discussionmentioning

confidence: 99%

An Alternative for the End-of-life Phase of Flame Retardant Textile Products: Degradation of Flame Retardant and Preliminary Settings of Energy Valorization by Gasification

Yasin¹,

Curti²,

Rovero³

et al. 2017

BioResources

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A study of pyrolysis and pyrolysis products of flame-retardant cotton fabrics by DSC, TGA, and PY–GC–MS

Cited by 234 publications

References 7 publications

An Overview of Mode of Action and Analytical Methods for Evaluation of Gas Phase Activities of Flame Retardants

An Overview of Mode of Action and Analytical Methods for Evaluation of Gas Phase Activities of Flame Retardants

Pyrolysis Characteristics of Phoenix Dactylifera Date Palm Seeds Using Thermo-Gravimetric Analysis (TGA)

An Alternative for the End-of-life Phase of Flame Retardant Textile Products: Degradation of Flame Retardant and Preliminary Settings of Energy Valorization by Gasification

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