Flame retardants (FRs) have been around us for decades to increase the chances of survival against fire or flame by limiting its propagation. The FR textiles, irrespective of their atmospheric presence are used in baby clothing, pushchairs, car seats, etc. The overall FR market in Asia, Europe, and the United States in 2007 was around 1.8 million metric tonnes. It is estimated that the worldwide consumption of FRs will reach 2.8 million tonnes in 2018. Unfortunately, a sustainable approach for textile waste, especially in the case of FR textiles, is absent. Incineration and landfill of FR textiles are hindered by various toxic outcomes. To address the need for sustainable methods of discarding FR textiles, the mechanical recycling of cotton curtains was evaluated.
The [Formula: see text]-methylol dimethyl phosphono propionamide (MDPA) flame retardant compounds are predominantly used for cotton fabric treatments with trimethylol melamine (TMM) to obtain better crosslinking and enhanced flame retardant properties. Nevertheless, such treatments are associated with a toxic issue of cancer-causing formaldehyde release. An eco-friendly finishing was used to get formaldehyde-free fixation of flame retardant to the cotton fabric. Citric acid as a crosslinking agent along with the sodium hypophosphite as a catalyst in the treatment was utilized. The process parameters of the treatment were enhanced for optimized flame retardant properties, in addition, low mechanical loss to the fabric by response surface methodology using Box–Behnken statistical design experiment methodology was achieved. The effects of concentrations on the fabric’s properties (flame retardancy and mechanical properties) were evaluated. The regression equations for the prediction of concentrations and mechanical properties of the fabric were also obtained for the eco-friendly treatment. The R-squared values of all the responses were above 0.95 for the reagents used, indicating the degree of relationship between the predicted values by the Box–Behnken design and the actual experimental results. It was also found that the concentration parameters (crosslinking reagents and catalysts) in the treatment formulation have a prime role in the overall performance of flame retardant cotton fabrics.
The initial setting up and preliminary tests on a square‐based spouted bed gasifier at pilot scale (20 kWth) have been investigated. The novel plant is composed of: a squared‐base spouted bed unit, a feeding system to regulate the biomass mass inflow, an air pump, a clean‐up system, and an online gas chromatograph analyzer to assess the quality of the produced gas. The profile of temperatures along the reactor has been monitored with different thermocouples during experimental tests. The start‐up process has been optimized to reduce the time to achieve stationary conditions. Two different materials (wood pellets and prunings from apple trees) have been tested at different feeding rates. Wood pellets were used to validate the performance of the spouted bed reactor and afterwards, residues of prunings from apple trees were validated as a suitable potential feedstock for energy recovery purposes. In addition, a representative sample of char from wood pellet gasification has been collected and characterized. In particular, the properties of specific surface area, pore size, and pore distribution have been measured by the Brunauer‐Emmett‐Teller method. The obtained outcomes represent one of the few available results in literature using a square‐based spouted bed reactor for the gasification of biomass at pilot scale.
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