A thirteen-level inverter based on switching capacitor is proposed in order to improve the boost capacity and output power quality of inverter in renewable energy power generation system. The proposed topology is composed of one DC input power supply, three capacitors and 14 switching devices, and achieves thirteen-level output with six times voltage boost. It has smaller volume, lower cost and output harmonic content. Moreover, it can realize inverter without H bridge and reduce the voltage stress of switching tube. In addition, the proposed inverter can achieve self-balancing capacitor voltage without any auxiliary method, simplifying the complexity of control. The superiority of the proposed topology is verified by comparing with other traditional multilevel inverters. The simulation and experimental verification on the simulation and prototype platform show that the inverter has good performance in both steady and dynamic conditions.