A novel 3-fold interpenetrated dia metal-organic framework as a heterogeneous catalyst for CO2 cycloaddition

Jiang, Wei; Yang, Jiaqi; Yan, Guosong; Liu, Bo; Qiao, Yu; Zhou, Tianyu; Wang, Jiajun; Che, Guangbo

doi:10.1016/j.inoche.2020.107770

Cited by 12 publications

(2 citation statements)

References 42 publications

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“…11,12 Over the years, research efforts to convert CO 2 to FA have been studied extensively using homogeneous systems. 13,14 A series of half-sandwich Ir(III) complexes realized the formation of FA from CO 2 at 25 °C and 1 bar by modulating the electron-donating effect of the ligands. 11 Transition metal catalyst systems have also been employed for the production of FA from CO 2 and H 2 at room temperature and atmospheric pressure in a homogeneous setup.…”

Section: ■ Introductionmentioning

confidence: 99%

Hydrogenation of Carbon Dioxide to Formate by Noble Metal Catalysts Supported on a Chemically Stable Lanthanum Rod-Metal–Organic Framework

et al. 2023

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The conversion of carbon dioxide to formate is of great importance for hydrogen storage as well as being a step to access an array of olefins. Herein, we have prepared a JMS-5 metal–organic framework (MOF) using a bipyridyl dicarboxylate linker, with the molecular formula [La2(bpdc)3/2(dmf)2(OAc)3]·dmf. The MOF was functionalized by cyclometalation using Pd(II), Pt(II), Ru(II), Rh(III), and Ir(III) complexes. All metal catalysts supported on JMS-5 showed activity for CO2 hydrogenation to formate, with Rh(III)@JMS-5a and Ir(III)@JMS-5a yielding 4319 and 5473 TON, respectively. X-ray photoelectron spectroscopy of the most active catalyst Ir(III)@JMS-5a revealed that the iridium binding energies shifted to lower values, consistent with formation of Ir–H active species during catalysis. The transmission electron microscopy images of the recovered catalysts of Ir(III)@JMS-5a and Rh(III)@JMS-5a did not show any nanoparticles. This suggests that the catalytic activity observed was due to Ir(III) and Rh(III). The high activity displayed by Ir(III)@JMS-5a and Rh(III)@JMS-5a compared to using the Ir(III) and Rh(III) complexes on their own is attributed to the stabilization of the Ir(III) and Rh(III) on the nitrogen and carbon atom of the MOF backbone.

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Section: ■ Introductionmentioning

confidence: 99%

Hydrogenation of Carbon Dioxide to Formate by Noble Metal Catalysts Supported on a Chemically Stable Lanthanum Rod-Metal–Organic Framework

et al. 2023

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“…Che and Liu et al reported an example of using JLNU-99 to catalyze this reaction, but they did not study the suitability of the catalyst for systems containing benzene rings. [18] Yan et al used bifunctional metal-doped ZIF-8, which can catalyze this reaction without co-catalyst and solvent. But they only reported the conversion of styrene oxide and there is no other epoxides.…”

Section: Introductionmentioning

confidence: 99%

Solvent‐Free CO₂ Fixation Reaction Catalyzed by MOFs Composites Containing Polycarboxylic Acid Ligands

et al. 2021

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Metal-Organic Frameworks (MOFs) have been used to catalyze the conversion of CO 2 to cyclic carbonates through cycloaddition reaction. A series of MOFs composites based on Cu-BTC (H 3 BTC, 1,3,5-Benzenetricarboxylic acid) were screened out by adjusting the ligands and loaded materials. Among them, Cu-BTC@ZnFe 2 O 4 achieved good yields in this reaction, and after several catalytic cycles, the yield also remained above 90 %. The larger the steric hindrance of epoxides used, the lower the yields of cycloaddition reaction. In addition, computational chemistry was used to explain this catalytic process. After adding the catalyst, the energy barrier of the initial step of the reaction was effectively reduced.

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Synthetic Origin-Dependent catalytic activity of Metal-Organic Frameworks: Unprecedented demonstration with ZIF-8 s on CO2 cycloaddition reaction

Lee

Jeong

et al. 2022

Chemical Engineering Journal

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A novel 3-fold interpenetrated dia metal-organic framework as a heterogeneous catalyst for CO2 cycloaddition

Cited by 12 publications

References 42 publications

Hydrogenation of Carbon Dioxide to Formate by Noble Metal Catalysts Supported on a Chemically Stable Lanthanum Rod-Metal–Organic Framework

Hydrogenation of Carbon Dioxide to Formate by Noble Metal Catalysts Supported on a Chemically Stable Lanthanum Rod-Metal–Organic Framework

Solvent‐Free CO₂ Fixation Reaction Catalyzed by MOFs Composites Containing Polycarboxylic Acid Ligands

Synthetic Origin-Dependent catalytic activity of Metal-Organic Frameworks: Unprecedented demonstration with ZIF-8 s on CO2 cycloaddition reaction

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A novel 3-fold interpenetrated dia metal-organic framework as a heterogeneous catalyst for CO2 cycloaddition

Cited by 12 publications

References 42 publications

Hydrogenation of Carbon Dioxide to Formate by Noble Metal Catalysts Supported on a Chemically Stable Lanthanum Rod-Metal–Organic Framework

Hydrogenation of Carbon Dioxide to Formate by Noble Metal Catalysts Supported on a Chemically Stable Lanthanum Rod-Metal–Organic Framework

Solvent‐Free CO2 Fixation Reaction Catalyzed by MOFs Composites Containing Polycarboxylic Acid Ligands

Synthetic Origin-Dependent catalytic activity of Metal-Organic Frameworks: Unprecedented demonstration with ZIF-8 s on CO2 cycloaddition reaction

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Product

Resources

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Solvent‐Free CO₂ Fixation Reaction Catalyzed by MOFs Composites Containing Polycarboxylic Acid Ligands