A gas chromatographic stationary of homochiral metal-peptide framework material and its applications

Li, Lang; Xie, Sheng‐Ming; Chen, Ling; Zhu, Pengjing

doi:10.1007/s40242-017-6270-3

Cited by 20 publications

(1 citation statement)

References 37 publications

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“…Therefore, obtaining a chiral monomer with high enantiopurity is of critical importance. For pharmacological research, efficient enantioseparation techniques are indispensable, such as high‐resolution gas chromatography (GC), high‐performance liquid chromatography (HPLC), capillary electrophoresis (CE), and so on.…”

Section: Introductionmentioning

confidence: 99%

A novel chiral inorganic mesoporous silica used as a stationary phase in GC

Yuan

et al. 2019

Chirality

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Chiral mesoporous silica (CMS) has attracted widespread attention because of some unique properties, such as high surface area, uniformly structured nanoscale cavities, and excellent chemical and thermal stability. In this work, we report the utilization of a CMS as the stationary phase for the separation of racemates in gas chromatography (GC). A CMS‐coated capillary column was fabricated by a dynamic coating method. Eighteen racemates belonging to different classes of organic compounds were separated on this column, including chiral alcohols, aldehydes, ketones, organic acids, halohydrocarbons, alkenes, alcohol amines, epoxides, and amino acid derivatives. In addition, linear alkanes, alcohols, and aromatic hydrocarbons have also been resolved.

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Section: Introductionmentioning

confidence: 99%

A novel chiral inorganic mesoporous silica used as a stationary phase in GC

Yuan

et al. 2019

Chirality

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The Rise of Metal–Organic Frameworks in Analytical Chemistry

Pacheco‐Fernández

González‐Hernández

Pasán

et al. 2019

Handbook of Smart Materials in Analytical Chemistry

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Recent advances of application of porous molecular cages for enantioselective recognition and separation

Xie

Yuan

2019

J of Separation Science

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Porous materials with well‐defined pore structures have received considerable attention in the past decades due to their unique structures and wide applications. Most porous materials such as zeolites, metal‐organic frameworks, covalent organic frameworks, and porous organic polymers are extended to infinite frameworks or networks by robust covalent or coordination bonds. Porous molecular cages composed of discrete molecules with permanent cavities are an emerging class of porous material and the discrete molecules assemble into solids by weak intermolecular interaction. In comparison to porous extended solids such as metal‐organic frameworks and covalent organic frameworks, porous molecular cage solids are generally soluble in organic solvents thus allowing solution processing, making them more convenient to apply in many fields. This review mainly focuses on the recent advances of application of porous molecular cages (porous organic cages and metal‐organic cages) for enantioselective recognition and separation from 2010 to present, including gas chromatography, capillary electrochromatography, chiral fluorescent recognition, chiral potentiometric sensing, and enantioselective adsorption. Furthermore, the two important family members of porous molecular cages, porous organic cages and metal‐organic cages, are also discussed.

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A gas chromatographic stationary of homochiral metal-peptide framework material and its applications

Cited by 20 publications

References 37 publications

A novel chiral inorganic mesoporous silica used as a stationary phase in GC

A novel chiral inorganic mesoporous silica used as a stationary phase in GC

The Rise of Metal–Organic Frameworks in Analytical Chemistry

Recent advances of application of porous molecular cages for enantioselective recognition and separation

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