various fabrics [7][8][9][10][11][12] and fibers [13][14][15] for fabricating triboelectric energy harvesters. Fabric-or fiber-based wearable energy harvesters facilitate lightweight energy generation systems that are comfortable for the wearer. [1] However, the output voltage of triboelectric energy harvesters is drastically reduced by adsorbed water molecules, [16] such as humidity originating from the body, rain, or other surrounding environmental conditions. In general, the output voltage of a triboelectric energy harvester is proportional to the charge density of the contact surface. [17] Under high relative humidity conditions, a thick adsorbed water layer increases the conductivity of the contact surface, causing dissipation of surface charges induced by triboelectrification to another material. [18,19] The decreased charge density of the contact surface results in the deterioration of the output voltage; therefore, there is motivation to develop a humidity-resistant, wearable, triboelectric energy harvester. To date, there have been some efforts to impart humidity resistance to triboelectric energy harvesters. [20][21][22][23][24][25][26] For example, Seol et al. reported a triboelectric vibrational energy harvester sealed in an acrylic tube to reduce the penetration of humidity; this device showed excellent resistance to ambient humidity. [20] Additionally, various methods for fabricating humidity-resistant triboelectric energy harvesters have been reported, including a hydrophobic microsponge structure, [21,22] nature-replicating micro-/nanostructure, [23] and micro/nanosurface morphologies [24,25] using polystyrene microbeads and natural materials with micro-/nanomorphologies as a template or mold. However, no further research has been undertaken to apply these techniques to fabric-based, wearable triboelectric energy harvesters.Kim et al. reported a fabric-based, wearable, humidityresistant triboelectric energy harvester by fabricating individual ZnO-polydimethylsiloxane core-shell fibers. [26] Each core-shell fiber was sealed at both sides by a polymer and then woven to prepare a fabric-based triboelectric energy harvester. This harvester showed excellent humidity resistance up to a relative humidity of 95%; however, the fabrication of the humidityresistant fabric is very complicated as it required the formation of nanostructures, fiber-combining, and sealing of each fiber.The development of fabric-based triboelectric energy harvesters is of great interest for converting human motion into electricity and is relevant for the development of wearable electronics. However, such harvesters exhibit significant degradation in performance under high humidity conditions. To solve this problem, a humidity-resistant, fabric-based triboelectric energy harvester by depositing self-assembled monolayers (SAM) to increase the hydrophobicity of the fabric surface is demonstrated. The SAM coating is compatible with various fabrics and a noticeable improvement in triboelectric performance under high humidity conditions...