The photocurrent conversions of transition metal dichalcogenide nanosheets are unprecedentedly impressive, making them great candidates for visible range photodetectors. Here we demonstrate a method for fabricating micron-thick, flexible films consisting of a variety of highly separated transition metal dichalcogenide nanosheets for excellent band-selective photodetection. Our method is based on the non-destructive modification of transition metal dichalcogenide sheets with amine-terminated polymers. The universal interaction between amine and transition metal resulted in scalable, stable and high concentration dispersions of a single to a few layers of numerous transition metal dichalcogenides. Our MoSe2 and MoS2 composites are highly photoconductive even at bending radii as low as 200 μm on illumination of near infrared and visible light, respectively. More interestingly, simple solution mixing of MoSe2 and MoS2 gives rise to blended composite films in which the photodetection properties were controllable. The MoS2/MoSe2 (5:5) film showed broad range photodetection suitable for both visible and near infrared spectra.
Self-powered energy harvesters utilizing triboelectric effect and electrostatic induction have been widely studied, leading in the materials viewpoint to numerous material pairs for facile charge separation upon repetitive contacts with elaborate topological structures. Here, we present a simple but robust triboelectric platform based on a molecularly engineered surface triboelectric nanogenerator by self-assembled monolayers (METS). Triboelectric surface charge density of a substrate was readily controlled by the variation of end-functional groups of self-assembled monolayers (SAMs). In particular, by employing fluorine terminated SAMs, we are able to develop a METS with the maximum open circuit voltage and short circuit current of 105 V and 27 μA, respectively, under relatively gentle mechanical contacts with the 3N vertical force at 1.25 Hz. The power density of the device was 1.8 W/m 2 at the load resistance of 10 MΩ more than 60 times greater than that of an unmodified dielectric/Al device. Moreover, our approach with SAMs was extended to various types of surfaces including fabrics of silk, cotton, and poly(ethylene terephthalate) (PET) and a PET film, and the results of singlefriction-surface triboelectric nanogenerators with these materials offers a facile and universal guideline for designing triboelectic materials.
Enhancing the device performance of organic memory devices while providing high optical transparency and mechanical flexibility requires an optimized combination of functional materials and smart device architecture design. However, it remains a great challenge to realize fully functional transparent and mechanically durable nonvolatile memory because of the limitations of conventional rigid, opaque metal electrodes. Here, we demonstrate ferroelectric nonvolatile memory devices that use graphene electrodes as the epitaxial growth substrate for crystalline poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE) polymer. The strong crystallographic interaction between PVDF-TrFE and graphene results in the orientation of the crystals with distinct symmetry, which is favorable for polarization switching upon the electric field. The epitaxial growth of PVDF-TrFE on a graphene layer thus provides excellent ferroelectric performance with high remnant polarization in metal/ferroelectric polymer/metal devices. Furthermore, a fully transparent and flexible array of ferroelectric field effect transistors was successfully realized by adopting transparent poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] semiconducting polymer.
A gas-driven ultrafast adhesion switching of water droplets on palladium-coated Si nanowire arrays is demonstrated. By regulating the gas-ambient between the atmosphere and H2 , the super-hydrophobic adhesion is repeatedly switched between water-repellent and water-adhesive. The capability of modulating the super-hydrophobic adhesion on a super-hydrophobic surface with a non-contact mode could be applicable to novel functional lab-on-a-chip platforms.
This paper presents a power-generating sensor array in a flexible and stretchable form. The proposed device is composed of resistive strain sensors, capacitive tactile sensors, and a triboelectric energy harvester in a single platform. The device is implemented in a woven textile structure by using proposed functional threads. A single functional thread is composed of a flexible hollow tube coated with silver nanowires on the outer surface and a conductive silver thread inside the tube. The total size of the device is 60 × 60 mm2 having a 5 × 5 array of sensor cell. The touch force in the vertical direction can be sensed by measuring the capacitance between the warp and weft functional threads. In addition, because silver nanowire layers provide piezoresistivity, the strain applied in the lateral direction can be detected by measuring the resistance of each thread. Last, with regard to the energy harvester, the maximum power and power density were measured as 201 μW and 0.48 W/m2, respectively, when the device was pushed in the vertical direction.
various fabrics [7][8][9][10][11][12] and fibers [13][14][15] for fabricating triboelectric energy harvesters. Fabric-or fiber-based wearable energy harvesters facilitate lightweight energy generation systems that are comfortable for the wearer. [1] However, the output voltage of triboelectric energy harvesters is drastically reduced by adsorbed water molecules, [16] such as humidity originating from the body, rain, or other surrounding environmental conditions. In general, the output voltage of a triboelectric energy harvester is proportional to the charge density of the contact surface. [17] Under high relative humidity conditions, a thick adsorbed water layer increases the conductivity of the contact surface, causing dissipation of surface charges induced by triboelectrification to another material. [18,19] The decreased charge density of the contact surface results in the deterioration of the output voltage; therefore, there is motivation to develop a humidity-resistant, wearable, triboelectric energy harvester. To date, there have been some efforts to impart humidity resistance to triboelectric energy harvesters. [20][21][22][23][24][25][26] For example, Seol et al. reported a triboelectric vibrational energy harvester sealed in an acrylic tube to reduce the penetration of humidity; this device showed excellent resistance to ambient humidity. [20] Additionally, various methods for fabricating humidity-resistant triboelectric energy harvesters have been reported, including a hydrophobic microsponge structure, [21,22] nature-replicating micro-/nanostructure, [23] and micro/nanosurface morphologies [24,25] using polystyrene microbeads and natural materials with micro-/nanomorphologies as a template or mold. However, no further research has been undertaken to apply these techniques to fabric-based, wearable triboelectric energy harvesters.Kim et al. reported a fabric-based, wearable, humidityresistant triboelectric energy harvester by fabricating individual ZnO-polydimethylsiloxane core-shell fibers. [26] Each core-shell fiber was sealed at both sides by a polymer and then woven to prepare a fabric-based triboelectric energy harvester. This harvester showed excellent humidity resistance up to a relative humidity of 95%; however, the fabrication of the humidityresistant fabric is very complicated as it required the formation of nanostructures, fiber-combining, and sealing of each fiber.The development of fabric-based triboelectric energy harvesters is of great interest for converting human motion into electricity and is relevant for the development of wearable electronics. However, such harvesters exhibit significant degradation in performance under high humidity conditions. To solve this problem, a humidity-resistant, fabric-based triboelectric energy harvester by depositing self-assembled monolayers (SAM) to increase the hydrophobicity of the fabric surface is demonstrated. The SAM coating is compatible with various fabrics and a noticeable improvement in triboelectric performance under high humidity conditions...
A triboelectric nanogenerators (TENG) are of great interest as emerging power harvesters because of their simple device architecture with unprecedented high efficiency. Despite the substantial development of new constituent materials and device architectures, a TENG with a switchable surface on a single device, which allows for facile control of the triboelectric output performance, remains a challenge. Here, a supramolecular route for fabricating a novel TENG based on an alkali‐metal‐bound porous film, where the alkali metal ions are readily switched among one another is demonstrated. The soft nanoporous TENG contains numerous SO3− groups on the surface of nanopores prepared from the supramolecular assembly of sulfonic‐acid‐terminated polystyrene and poly(2‐vinylpyridine) (P2VP), followed by soft etching of P2VP. Selective binding of alkali metal ions, including Li+, Na+, K+, and Cs+, with SO3− groups enables the development of mechanically robust alkali‐metal‐ion‐decorated TENGs. The triboelectric output performance of the devices strongly depends on the alkali metal ion species, and the output power ranges from 11.5 to 256.5 µW. This wide‐range triboelectric tuning can be achieved simply by a conventional ion exchange process in a reversible manner, thereby allowing reversible control of the output performance in a single device platform.
Supramolecular assembly through complementary interaction between molecular subgroups belonging to phase-separating polymer species offers a great opportunity, not only for constructing nanoscale soft templates reminiscent of conventional block copolymer morphologies, but also for tailoring surface properties by facile removal of one of the structure components by cleaving complementary interactions. Herein we report the fabrication of a novel, organic, nanoporous film through supramolecular assembly of two complementarily, end-interacting, mono-end-functionalized polymers under solvent annealing. The film of end-functionalized polymer blends under solvent annealing yielded phase-separated nanodomains that resemble nanoscopically ordered structures of block copolymers, but that are more advantageous due to easily cleavable and exchangeable links between the phase-separated domains. The removal of one of the components of the precursor structure formed from the end-functionalized polymers through cleavage of complementary interactions allowed us to fabricate mono- or multilayered nanoporous structures in which the chemically useful end-functionalities of the remnant polymers are rich on the surface of the pores. The resultant, organic, nanoporous films with tailored surface functionality offer a useful platform for various chemical and biological applications.
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